In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea +9 more
wiley +1 more source
Correction: Alkaline electrocatalytic water oxidation by Fe-Ni nanostructures on porous turbostratic carbon with tailorable metal-metal active sites. [PDF]
Saha D +12 more
europepmc +1 more source
Stabilizing Frustrated Phase Transitions in Selective Oxidation Reactions
Using multimodal operando spectromicroscopy, the frustrated phase transition responsible for selective oxidation over cobalt oxide spinel catalysts is identified, corresponding to combined surface reaction and Mars‐van Krevelen (MvK) dynamics. This regime is disrupted by the formation of mobile vacancies and the depletion of active oxygen at high ...
Luis Sandoval‐Diaz +11 more
wiley +1 more source
Can five chemically different lamellar crystals self-assemble in a single spherulite? [PDF]
Matxinandiarena E +6 more
europepmc +1 more source
Electron Channeling Contrast Imaging of Ferroelastic Domains
A simple scanning electron microscopy technique, electron channeling contrast imaging, unveils nanoscale ferroelastic domains and their coupling to functional properties in oxide heterostructures. The work demonstrates high‐resolution mapping of both surface and buried domains, broadening the experimental toolbox for ferroic and quantum oxide systems ...
Wei Peng +13 more
wiley +1 more source
Operando X-ray imaging reveals size-dependent evolution of cobalt oxide thermochemical material during thermal redox cycles. [PDF]
Peng Y +11 more
europepmc +1 more source
Improving Ionic Conformality Across Polymer Electrolyte|Electrode Interfaces
Polymer electrolytes typically form physically intimate electrode interfaces but often fail to maintain continuous ionic pathways, critically limiting battery performance. Through strategic compositional design, this study introduces a molecular ionic composite electrolyte that effectively reduces interfacial ionic depletion, ensuring consistent ion ...
Jungki Min +12 more
wiley +1 more source
Decoding the bonding in Nd<sub>2</sub>Fe<sub>14</sub>B: a synchrotron charge density perspective on a rare-earth magnet. [PDF]
Chen YS.
europepmc +1 more source
A synergistic combination of a highly reversible host and a commercially viable carbonate‐rich electrolyte enables simultaneous stabilization of both anode and cathode interfaces in anode‐free lithium metal batteries. This integrated strategy delivers exceptional reversibility and a record volumetric energy density of 1270 Wh L−1 (including package) in
Dong‐Yeob Han +9 more
wiley +1 more source

