Results 181 to 190 of about 1,196,212 (240)

Reprogramming rumen hydrogen economy for methane mitigation to fulfill the climate goal. [PDF]

Innovation (Camb)
Li Q, Zhang X, Wang R, Fu B, Hess M, Tan Z, Wang M.   +6 more
europepmc   +1 more source

A New Spin on Photocatalysis: Vortex Fluidic‐Driven Photooxidations Enabled by Solution‐Processable Microporous Polymers

Chemistry – A European Journal, EarlyView.
Newly developed polymers with intrinsic microporosity (PIMs) were combined with benzo[c][1,2,5]thiadiazole (BTZ) to be used as visible light photocatalytic coatings on the Vortex Fluidic Device (VFD). The VFD's rapid rotation and continuous flow capabilities enhanced singlet oxygen and superoxide radical reactions, achieving a dramatic eightfold ...
Leonardo Amicosante, Fiona R. Gordon, Dominic Taylor, Neil B. McKeown, Daniel M. Jubb, Stuart R. Kennedy, Marc A. Little, Filipe Vilela, Colin L. Raston, Scott J. Dalgarno   +9 more
wiley   +1 more source

Accelerating Electrolyte Discovery Using Generative Models and Molecular Dynamics Simulations. [PDF]

ACS Omega
Deerattrakul V, Duangdangchote S, Boonchun A, Iamprasertkun P.   +3 more
europepmc   +1 more source

Controlled Formation and Unusual Reactivity of Cyanohexatriyne (HC7N), a Synthetically Challenging Interstellar Cyanopolyyne

Chemistry – A European Journal, EarlyView.
First controlled formation of cyanohexatriyne (HC7N) is achieved using a cobalt–alkyne masking strategy that overcomes the intrinsic instability of nitrile‐substituted polyynes. The approach enables spectroscopic validation of HC7N and reveals its pronounced electrophilicity through a selective conjugate addition with diethylamine.
Léa Lefrançois, Mano Cremer, Thierry Roisnel, Jean‐Claude Guillemin, Yann Trolez   +4 more
wiley   +1 more source

Exploring internal and external drivers of hydrogen deployment in the energy transition. [PDF]

iScience
Xie Z, Fernandes R, Andresen GB.
europepmc   +1 more source

The Rich Chemistry of Ionized Methanol With Sulfur Dioxide: Pathways to Prebiotic and Elusive Species in Earth's Atmosphere and Space

Chemistry – A European Journal, EarlyView.
The reaction between the methanol radical cation and sulfur dioxide is remarkably fast and forms several ionic and neutral products (HOSOH+, CH2OSO+, CH2OH+, CH2O, H2O, HSO2). The chemistry goes beyond simple proton or hydrogen transfer, revealing a close interaction between the two species, relevant to atmospheric and astrochemical environments where ...
Mauro Satta, Daniele Catone, Mattea Carmen Castrovilli, Antonella Cartoni   +3 more
wiley   +1 more source

Ni(ii) catalysed dehydrogenative coupling of alcohols with indoles: access to bis(indolyl)methanes. [PDF]

RSC Adv
Beril Victoriya V, Balasubramani K, Britto S.   +2 more
europepmc   +1 more source

Ni2‐Imido Bispincer Platforms: Cooperative Reactivity Enabled Through Substrate Addition Across a Ni2N Unit

Chemistry – A European Journal, EarlyView.
Ni2 bispincer complexes with an embedded central imido anchor are presented. The bispincer complexes leverage the high basicity of imido ligands to facilitate 1,2 addition of weak B─H and Si─H bonds, resulting in hydrido–amido complexes and resultingly a contortion of a Ni─Ni sigma bond to form an S = 1 species. The 1,2 addition is proposed to serve as
David de los Santos, Kritika Gour, Manar M. Shoshani   +2 more
wiley   +1 more source

Directed Construction of Hierarchical Porous Carbon With Ultrahigh Surface Area for High-Density Methane Storage at Room Temperature. [PDF]

Adv Mater
Sun Y, Wu H, Yan Y, Ma S, Nie W, Xu X, Ren H, Wu X.   +7 more
europepmc   +1 more source

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

Chemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz, Sven Schaefer, Oksana Storcheva, Gabriele Raudaschl‐Sieber, Johannes Bitzer, Wolfgang Kleist, Klaus Köhler   +6 more
wiley   +1 more source