Results 181 to 190 of about 1,039,813 (285)

Carbon dots in electrochemiluminescence: Mechanisms, interface engineering, and bioanalytical applications

open access: yesResponsive Materials, EarlyView.
Carbon dots are emerging as versatile electrochemiluminescent nanomaterials whose structure, surface states, and interfacial design jointly determine ECL pathways and performance. This review highlights how mechanistic understanding and materials engineering enable programmable CD‐ECL systems for bioanalysis, imaging, and future intelligent analytical ...
Yuhan Zhao, Zixuan Chen, Jun‐Jie Zhu
wiley   +1 more source

Acid Resistant and Highly Silver Selective Membranes Based on Charged Nanoporous 2D‐Materials

open access: yesSmall, EarlyView.
In this work, new membranes based on charged & nanoporous nanosheets with unprecedented selectivity to silver versus a wide range of other metallic ions are reported. Furthermore, a demonstrated and lead specific intralamellar lead pathway is demonstrated. A potential applicability for ubiquitous silver in WEEE is validated.
Sarah M. Chevrier   +6 more
wiley   +1 more source

Characterization of the Pore Environments in Covalent Organic Frameworks by Dynamic Spin Probe Exchange

open access: yesSmall, EarlyView.
Covalent organic frameworks (COFs) with alkyl or triethylene glycol pore linings are probed with water‐dissolved nitroxide radicals using CW EPR spectroscopy. Adsorption affinity, local polarity, and radical concentration inside the pores are quantified, revealing hydrogen bonding, dipolar, and π‐π interactions that govern guest binding, which ...
Sebastian Michler   +5 more
wiley   +1 more source

Rhodium Cluster Catalysts Enable Efficient Catalytic Hydroformylation in Mild Conditions: Cluster Size Dependence

open access: yesSmall, EarlyView.
Nanometer‐sized Rh clusters provide a specific reaction environment that facilitates the balanced co‐adsorption of styrene, CO, and H, thereby promoting hydroformylation. ABSTRACT The size of the reactive metal domain, termed an ‘ensemble’, in supported metal catalysts critically influences their catalytic activity.
Yuki Nakaya   +5 more
wiley   +1 more source

Adsorption‐Programmed Transformation of a Two‐Dimensional Cu–Imidazolate Framework into Mn‐Integrated Catalytic Nanonetwork

open access: yesSmall, EarlyView.
A freeze‐dried copper‐based metal‐organic framework removes more than 95% of manganese from water. Capturing the metal reorganizes the framework, giving the used adsorbent a second life as a reusable catalyst that produces valuable ester products in yields up to 84%.
Prathmesh Bhadane   +7 more
wiley   +1 more source

The Host‐Guest Assemblies of Metal–Organic Frameworks and Protic Ionic Liquids With ZIF‐8 and [Dema][TfO] – Structural Response and Ionic Conductivity

open access: yesSmall, EarlyView.
MOFs can serve as effective proton conductors owing to their porous structures and well‐defined channels. In this study, the protic ionic liquid [Dema][TfO] is introduced into ZIF‐8 cages. The confined [Dema][TfO] can transfer between adjacent ZIF‐8 cages, inducing cage expansion through the swing effect.
Wen Yang   +7 more
wiley   +1 more source

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