Results 91 to 100 of about 20,817 (265)

Visible‐Light Driven Acetylene Semi‐Hydrogenation to Ethylene With a Copper Photosensitizer and a Cobaloxime Catalyst

open access: yesChemistry – A European Journal, EarlyView.
A fully noble‐metal‐free photocatalytic system that couples cobaloxime catalysis with Cu photosensitizer for HAT‐driven acetylene‐to‐ethylene conversion is reported. ABSTRACT The purification of ethylene streams from acetylene impurities remains a key industrial challenge, for which light‐powered strategies are emerging as sustainable alternatives to ...
Anna Fortunato   +5 more
wiley   +1 more source

First Operation Results of a Methanol Demonstration Plant With Real Steel Mill Gases

open access: yesChemie Ingenieur Technik, EarlyView.
A demonstration plant with industrial setup regarding length, diameter, boiling water cooling system and gas recycle was initially operated with cleaned blast furnace gas and compared with earlier experiments with bottle gases. Dynamic disturbances from the steel mill and gas cleaning unit were noticed and could be compensated by the control system ...
Johannes Michael Voß, Tim Schulzke
wiley   +1 more source

A study of Ni‐Co/CeO2 catalyst derived from metal–organic framework for dry reforming of methane

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The efficacy of cobalt‐doped, MOF‐derived catalysts for dry reforming of methane (DRM) was examined. The focus was on the influence of varying nickel and cobalt molar ratios on catalytic performance. Three catalysts with Ni:Co ratios of 1:1, 1:0.5, and 0.5:1, were synthesized and tested with cerium oxide as a constant support. The DRM reaction
Ruth D. Alli, Nader Mahinpey
wiley   +1 more source

Microwave‐assisted catalytic pyrolysis of textile wastes: Synergistic effects and product characteristics

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study examines the microwave‐assisted catalytic pyrolysis (MACP) of individual and blended textiles (cotton, polyester, nylon 6) using ZnO and a ZnO/natural zeolite catalyst. In a custom‐built microwave reactor operated at 500°C, 1 kW power, and a 15‐min residence time, textile wastes were pyrolyzed.
Peyman Alizadeh   +3 more
wiley   +1 more source

Fetal gestational age estimation using ultrasonic transverse cerebellar diameter in a sub-saharan African population

open access: yesJournal of Medical Ultrasound
Background: To explore the relationship between fetal Transverse Cerebellar Diameter (TCD) and menstrual gestational age (GA) and to generate normative references (nomogram) of the fetal TCD in some pregnant women in Southwest Nigeria.
Akeem Olajide Adelabu   +3 more
doaj   +1 more source

Molten‐Salt‐Mediated Chemical Looping Oxidative Dehydrogenation of Ethane with In‐Situ Carbon Capture and Utilization

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
A sustainable alternative to steam cracking, the molten‐salt‐mediated oxidative dehydrogenation (MM‐ODH) of ethane (C2H6) in Li2CO3‐Na2CO3‐K2CO3 (LNK) couples thermal cracking with melt‐mediated CO2 capture to realize commercially competitive C2H4 and CO yields. LNK composition strongly influences MM‐ODH process outcomes.
Kyle Vogt‐Lowell   +6 more
wiley   +1 more source

Temperature‐Dependent Kinetics of Plasma‐Based CO2 Conversion: Interplay of Electron‐Driven and Thermal‐Driven Chemistry

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The transformation of CO2 into chemical building blocks is essential for a net‐zero energy future. Plasma‐chemical processing offers promising potential to achieve this. Here, we explore a temperature‐dependent plasma‐chemical reaction mechanism, revealing a shift from electron‐driven to thermal‐driven CO2 conversion regimes.
Aswath Mohanan   +2 more
wiley   +1 more source

Nitrogen‐Site Isomerism Unlocks Exciton Dissociation in Vinylene‐Linked COF‐Based Photocatalysts

open access: yesEcoEnergy, EarlyView.
Two regioisomeric vinylene‐linked covalent organic frameworks (COFs) constructed from diazine units with different nitrogen positions are developed for photocatalytic hydrogen evolution reaction (HER). Although structurally similar, the isomeric COFs exhibit distinct electron distribution and charge‐separation behaviors, leading to a more than twofold ...
Ming Wang   +10 more
wiley   +1 more source

Synergistic Engineering of Oxygen Vacancies and Topological Surface States in Bi2Te3/TiO2‐X Heterostructures for Highly Efficient Photothermal‐Driven CO2 Photoreduction

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Integrating the topological insulator Bi2Te3 with oxygen‐deficient TiO2‐X creates a synergistic platform for full‐spectrum CO2 reduction, achieving high‐selectivity C2+ production via enhanced photothermal catalysis and tailored charge dynamics.
Bingke Zhang   +11 more
wiley   +1 more source

Rational Design of CdS QDs/CeO2 Nanocube S‐Scheme Heterojunctions for Highly Efficient C2H4 Scavenging in Fresh Produce Preservation

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel S‐scheme heterojunction of CdS quantum dots on CeO2 nanocubes was designed to enhance charge separation and oxygen activation for efficient photocatalytic ethylene removal. The optimized composite achieved complete C2H4 degradation within 4 min under low‐intensity visible light, with a rate constant of 1.72 min−1. Mechanistic analysis confirmed
Zining Xu   +7 more
wiley   +1 more source

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