Results 331 to 340 of about 1,629,505 (387)

Cupin‐Type Dimethylsulfoniopropionate Lyase from Pelagibacter ubique (DddKPu) Catalyzes Aza‐Michael Addition of Primary and Secondary Amines to Acrylic Acid

open access: yesAngewandte Chemie, EarlyView.
A dimethylsulfoniopropionate lyase (DddK) was identified as an efficient aza‐Michaelase for the addition of amines to acrylate. Screening 74 amines with wild‐type DddK and its W26G variant yielded N‐substituted and N,N‐disubstituted β‐amino acids in 30%–93% isolated yield.
Diletta Arceri   +5 more
wiley   +1 more source

Bis(azuleno)pentalenes with Six Consecutive Odd‐Membered Rings

open access: yesAngewandte Chemie, EarlyView.
A new class of non‐alternant, non‐benzenoid polycyclic hydrocarbons with a unique 7‐5‐5‐5‐5‐7 odd‐membered ring topology has been synthesized. These compounds possess distinct electronic structures that integrate aromatic azulene and antiaromatic pentalene units, resulting in narrow band gaps, near‐infrared absorption, reversible acid‐base ...
Qing Jiang   +6 more
wiley   +1 more source

Aktivierung reduktiver Stickstoffspezies durch gepulste Elektrolyse: Aktuelle Fortschritte und Zukunftsaussichten

open access: yesAngewandte Chemie, EarlyView.
Die gepulste Elektrolyse ermöglicht die selektive Reduktion von Stickstoffspezies durch dynamische Anpassung der Oberflächen von Elektrokatalysatoren und lokalen Reaktionsmikroumgebungen. Dieser Minireview beleuchtet Fortschritte bei der Herstellung von Ammoniak und C–N‐gekoppelten organischen Stickstoffverbindungen unter gepulsten ...
Kiarash Torabi   +9 more
wiley   +1 more source

Organocatalyzed Atom Transfer Radical Polymerization (O‐ATRP) Using a Super‐Reducing Photoredox Catalyst

open access: yesAngewandte Chemie, EarlyView.
A super‐reducing organic photocatalyst expands the scope of O‐ATRP to challenging initiators and monomers. The system enables controlled polymerizations with air tolerance, temporal regulation, and grafting‐from strategies, highlighting the transformative potential of super‐reducing PCs in reversible‐deactivation radical polymerization.
Yucheng Zhao   +9 more
wiley   +1 more source

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