Results 121 to 130 of about 2,884 (278)

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

Chemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz, Sven Schaefer, Oksana Storcheva, Gabriele Raudaschl‐Sieber, Johannes Bitzer, Wolfgang Kleist, Klaus Köhler   +6 more
wiley   +1 more source

Bimolecular homolytic substitution of dialkyl selenides and tellurides with tri-n-butyltin radicals

, 1976
The rate constants for the SH2 reactions of tri-n-butyltin radicals with several dialkyl selenides and tellurides have been measured by EPR spectroscopy.
J.C. Scaiano, K.U. Ingold, P. Schmid, Schmid, P., Ingold, K. U., Scaiano, J.C.   +5 more
core   +1 more source

Achievement of Transition Metal Chalcogenides/Oxides in Hydrogen Production by Seawater Electrolysis

EcoEnergy, EarlyView.
Transition metal chalcogenides (TMCs)/oxides have shown great application potential in seawater splitting for hydrogen generation due to their adjustable electronic properties, abundant active sites, and excellent catalytic performance. ABSTRACT Under the impetus of global “dual carbon” goals, green hydrogen has become a key component of the future ...
Xiaohui Du, Xinyu Li, Jianna Li, Tao Sun
wiley   +1 more source

Large Nernst effect in Te-based van der Waals materials

Physical Review Research
Layered van der Waals tellurides reveal topologically nontrivial properties that give rise to unconventional magneto-transport phenomena. Additionally, their semimetallic character with high mobility makes them promising candidates for large magneto ...
M. Behnami, M. Gillig, A. G. Moghaddam, D. V. Efremov, G. Shipunov, B. R. Piening, I. V. Morozov, S. Aswartham, J. Dufouleur, K. Ochkan, J. Zemen, V. Kocsis, C. Hess, M. Putti, B. Büchner, F. Caglieris, H. Reichlova   +16 more
doaj   +1 more source

Design and Operation of Photovoltaic‐Driven Electrocatalytic Water Splitting for Hydrogen Production

EcoEnergy, EarlyView.
Photovoltaic‐driven electrocatalytic water splitting offers a scalable route to green hydrogen. This review introduces fundamental photovoltaic principles and key PV performance metrics, compares different PV–EC configurations, and provides practical guidance on design, operation, and PV–EC matching. Key bottlenecks and future directions for efficiency
Zhenlan Dou, Ying Zhang, Chunyan Zhang, Jieshi Shen, Miaoqiu Hu, Haifei Wang, Lei Guo   +6 more
wiley   +1 more source

Synergistic Engineering of Oxygen Vacancies and Topological Surface States in Bi2Te3/TiO2‐X Heterostructures for Highly Efficient Photothermal‐Driven CO2 Photoreduction

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Integrating the topological insulator Bi2Te3 with oxygen‐deficient TiO2‐X creates a synergistic platform for full‐spectrum CO2 reduction, achieving high‐selectivity C2+ production via enhanced photothermal catalysis and tailored charge dynamics.
Bingke Zhang, Chenchen Zhao, Jing Qiao, Changcun Li, Yang Wang, Xingshuo Liu, Dongbo Wang, Gang Liu, Zhao Qian, Rajeev Ahuja, Jinzhong Wang, Degang Zhao   +11 more
wiley   +1 more source

Asymmetric Dual‐Electron Bridge Via Gradient Orbital Coupling for Robust Alkaline Oxygen Evolution in Low‐Iridium Water Electrolysis

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The engineered IrOx/FeEu‐NiTex composite, with ultralow Eu (0.72 at%) and Ir (0.14 at%) content, harnesses an asymmetric dual‐electron‐bridge structure (Ni 3d–O 2p–Eu 4f, Ni 3d–O 2p–Ir 5d) for gradient orbital coupling. This unique architecture delivers superior and robust alkaline oxygen evolution activity, enabling efficient low‐iridium water ...
Guiling Wu, Qianlin Chen, Feng Wang, Yan Zhao, Zhaoyang Wang   +4 more
wiley   +1 more source

Bonanza-grade accumulations of gold tellurides in the Early Cretaceous Sandaowanzi deposit, northeast China

, 2013
The Sandaowanzi epithermal gold deposit (0.5. Moz or ca. 14. tons), located at the northern edge of the Great Xing'an range, NE China, is unique in that nearly all the gold (> 95%) is contained in gold tellurides mostly in bonanza grade ore shoots (the ...
Zhao, S., Lu, J., Cook, N., Liu, J., Zhao, Z., Zhang, Z., Zhao, H.   +6 more
core   +1 more source

Tellurium Electrochemistry: From Mechanistic Analysis in Diverse Electrolytic Media to Advanced Energy Storage Applications

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
As a metalloid with broad prospects in advanced applications, Te has not been fully clarified in terms of its intricate electrochemical behaviors across varied systems. This review systematically integrates fundamental electrochemical mechanisms, reaction kinetics identifications, and device application insights, establishing a comprehensive framework ...
Meng Zhang, Jiguo Tu, R. Vasant Kumar, Libo Chen, Tangkai Wu, Lili Jiang, Shuqiang Jiao   +6 more
wiley   +1 more source

Lattice‐Strained Cu2O‐Ni/NiO Heterostructure Enables Selective Electrocatalytic C–C Coupling of Alcohols to Cinnamaldehyde in Aqueous Medium

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study achieved the selective oxidation C–C coupling of PhCH2OH with EtOH to form cinnamaldehyde (CAL) on a designed Cu2O‐Ni/NiO heterojunction catalyst. By employing a salt precipitation strategy to balance the pH and cation concentration, an 86% conversion rate of PhCH2OH and a 67% high selectivity for CAL were realized.
Tian Cheng, Kaizhi Gu, Jiani Liu, Yujing Liu, Jianlong Wei, Zhaoling Ma, Hengyue Xu, Jia Zhang, Hanwen Liu, Yiqiong Zhang, Shuangyin Wang   +10 more
wiley   +1 more source