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Synthesis and Pyrolysis of Tetrahydro-1,4-oxazine-3,5-diones and Tetrahydro-1,4-thiazine-3,5-diones
Chemistry of Heterocyclic Compounds, 2001The preparation and characterization of six 4-substituted tetrahydro-l,4-oxazine-3,5-diones and five 4-substituted tetrahydro-l,4-thiazine-3,5-diones is described. Upon flash vacuum pyrolysis at 700°C these give N-substituted acetamides and nitriles, and a mechanism for formation of these products is proposed.
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