Results 1 to 10 of about 200 (108)
Nano-SiO2/DBN: an efficacious and reusable catalyst for one-pot synthesis of tetrahydrobenzo[b]pyran derivatives. [PDF]
Abstract Background: The nano-sized particles enhance the exposed surface area of the active part of the catalyst, thereby increasing the contact between precursors and catalyst considerably. In this study, nano-SiO2/1,5-diazabicyclo[4.3.0]non-5-en was synthesized, characterized and used as a heterogeneous nanocatalyst for the ...
Mehravar M +3 more
europepmc +6 more sources
A novel recyclable hydrolyzed nanomagnetic copolymer catalyst for green, and one-pot synthesis of tetrahydrobenzo[b]pyrans. [PDF]
Polymer-based catalysts have garnered significant interest for their efficiency, reusability, and compatibility with various synthesis processes. In catalytic applications, polymers offer the advantage of structural versatility, enabling functional groups to be tailored for specific catalytic activities.
Maleki B +5 more
europepmc +4 more sources
A facile and one-pot synthesis of new tetrahydrobenzo[b]pyrans in water under microwave irradiation. [PDF]
AbstractEleven new tetrahydrobenzo[b]pyran derivatives were synthesized via a three component reaction of different aromatic aldehydes, methyl cyanoacetate and 1,3-cyclohexadione, with water as solvent under catalyst-free microwave irradiation. The structures of all the new molecules were well analysed and their structures established by using various ...
Khumalo MR +3 more
europepmc +5 more sources
Novel 5,6,7,8-tetrahydrobenzo[b]pyran Derivatives: Synthesis and Anticancer Activity
Many new cyclized pyran systems with a potential anti-cancer activity were designed and prepared. Pyran systems showed high reactivity to various chemical reagents. 24 products of the prepared compounds were chosen and tested in (mM) as respectable anticancer factors.
Amira E M, Abdallah +3 more
openaire +2 more sources
Abstract Fused coumarins, because of their remarkable biological and therapeutic properties, particularly pyranocoumarins, have caught the interest of synthetic organic chemists, leading to the development of more efficient and environmentally friendly protocols for synthesizing pyranocoumarin derivatives.
Jayalakshmi M +3 more
wiley +1 more source
The Green and Efficient One-pot Synthesis of Tetrahydrobenzo[b]pyran Derivatives
Glutamic acid is used as an efficient organocatalyst for one-pot synthesis of tetrahydrobenzo [b]pyran via condensation of an aromatic aldehyde, dimedone and malononitrile in ethanol: water (1:4) as solvent at reflux temperature. The short reaction time, cleaner reaction, and easy workup make this protocol practical and economically attractive.
Bhaskar P. Ankush +2 more
openaire +2 more sources
Oxidative N‐Heterocyclic Carbene Catalysis
The advances in oxidative N‐heterocyclic carbene (NHC)‐catalysis are reviewed according to the strategies that rely on typical NHC‐bound intermediates, including acyl/imidoyl azolium, α,β‐unsaturated acyl azolium, and azolium peroxide species, as well as NHC‐derived ortho‐quinone methide (o‐QM), aza‐fulvene, and triaza‐diene intermediates, with ...
Carmela De Risi +5 more
wiley +1 more source
Tacrine is a drug used in the treatment of Alzheimer’s disease as a cognitive enhancer and inhibitor of the enzyme acetylcholinesterase (AChE). However, its clinical application has been restricted due to its poor therapeutic efficacy and high prevalence of detrimental effects.
Saikat Mitra +11 more
wiley +1 more source
Ecological release from herbivory due to chemical novelty is predicted to facilitate biological invasions by plants, but has not been tested on a community scale. We used metabolomics to assess the chemical novelty of invasive plant species at a site in eastern North America.
Brian E. Sedio +5 more
wiley +1 more source
Fructose-catalyzed synthesis of tetrahydrobenzo[b]pyran derivatives: Investigation of kinetics and mechanism [PDF]
Abstract Fructose was used as an efficient catalyst for three-component condensation reactions of aryl aldehydes, malononitrile, and dimedone in a mixture of EtOH and H2O as green solvents. The advantages of this method are a short reaction time, high yields, low cost, easy accesses, and simple work-up.
Sayyedeh Shadfar Pourpanah +2 more
openaire +1 more source

