Results 21 to 30 of about 1,718 (155)
2,3-Dichloro-5,6-Dicyano-1,4-Benzoquinone (DDQ)-Mediated CC Bond Formation: Redox Strategies from Stoichiometric to Catalytic Systems. [PDF]
2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone serves as a versatile oxidant and redox catalyst for CC bond formation through hydride abstraction or single‐electron transfer. Stoichiometric and catalytic systems enable benzylic, allylic, and aromatic CH activation under mild, metal‐free conditions, providing sustainable routes to complex and bioactive ...
Cha D, Min SJ.
europepmc +2 more sources
The title compounds were prepared by reaction of 6-acetyltetralin (1) with different aromatic aldehydes 2a-c, namely 2,6-dichlorobenzaldehyde, 2,6-diflouro-benzaldehyde, and 3-ethoxy-4-hydroxybenzaldehyde, to yield the corresponding a,b-unsaturated ...
Ebtehal S. Al-Abdullah
doaj +1 more source
SOME NEW ALKAMINES IN THE TETRAHYDRONAPHTHALENE SERIES [PDF]
GERALD G. WOODS, NATHAN B. EDDY
openaire +2 more sources
Catalytic enantioselective synthesis of trifluoromethylthiolated molecules remains a challenge. Here, the authors report a bifunctional selenide-catalyzed approach for the synthesis of structurally complex chiral trifluoromethylthiolated ...
Jie Luo +3 more
doaj +1 more source
Topology‐Dependent Coke Formation in the Catalytic Pyrolysis of Phenol Over HFAU and HZSM‐5 Zeolites
The coke formation and speciation during the catalytic pyrolysis of lignin over different zeolite topologies were studied with a combination of operando EPR spectroscopy and ex situ pulsed techniques aided with DFT calculations. Operando EPR data showed that the coke formation in HFAU is fast compared to HZSM‐5.
Jörg W. A. Fischer +6 more
wiley +2 more sources
β-Hydroxy carbocation intermediates in solvolyses of di- and tetra-hydronaphthalene substrates
Solvolysis of trichloroacetate esters of 2-methoxy-1,2-dihydro-1-naphthols shows a remarkably large difference in rates between the cis and trans isomers, kcis/ktrans = 1800 in aqueous acetonitrile.
Jaya S. Kudavalli +1 more
doaj +1 more source
It is found that the reaction of dimethyl 2-phenylcyclopropane-1,1-dicarboxylate with 2 equivalents each of aromatic aldehydes and TaCl5 in 1,2-dichloroethane at 23 °C for 24 h after hydrolysis gives substituted 4-phenyl-3,4-dihydronaphtalene-2,2(1H ...
Tat’yana P. Zosim +5 more
doaj +1 more source
Structure and Dissociation Pathways of Protonated Tetralin (1,2,3,4-Tetrahydronaphthalene) [PDF]
The infrared multiple-photon dissociation (IRMPD) spectrum of protonated tetralin (1,2,3,4-tetrahydronaphthalene, THN) has been recorded using an infrared free electron laser coupled to a Fourier transform ion cyclotron mass spectrometer. IR-induced fragmentation of the protonated parent [THN + H] +, m/z 133, yielded a single fragment ion at m/z 91. No
Martin Vala, Jos Oomens, Giel Berden
openaire +3 more sources
A triflate‐functionalized Ni–Ce/MOF–OTf superacid enables low‐temperature (∼140°C) in situ upgrading of ultra‐deep heavy oil. It reduces viscosity by 92.11% in 12 h, maintains activity over cycles, and delivers 90.25% recovery with a lower carbon footprint by selective bond cleavage. ABSTRACT Ultra‐deep heavy oil is an important unconventional resource,
Li Wang +5 more
wiley +1 more source
This study investigates the stability of TPD‐3F:FCC‐Cl blends under indoor conditions with various cosolvents and additives. The results reveal significant burn‐in degradation due to morphological instability under mild testing conditions. However, the DBDMF solid additive demonstrates improved stability, attributed to its lower miscibility and more ...
Ignacio Ballesteros García +13 more
wiley +1 more source

