Efficiency and stability of PSF OLEDs can be obtained by improving the terminal emitters (TE's) extinction coefficient (ε) and a large spectral overlap (J) with PS emission, combined with a dual‐channel energy transfer process, with a high T1 exciplex host system to suppress the back energy transfer (BET) from PS to the host and a high intrinsic stable
Odugu Pavan Kumar +4 more
wiley +1 more source
The extended π‐system and low‐lying n‐π∗ transition endow DDOBDiKTa with a synergistic combination of strong spin‐orbit coupling, small reorganization energy and small ΔEST, enabling this blue boron‐nitrogen‐carbonyl hybrid emitter to achieve a fast kRISC of 6.34 × 106 s−1 together with OLEDs showing small efficiency roll‐off, with EQEmax/EQE10000 of ...
Wenrui Wang +6 more
wiley +2 more sources
Asymmetric Diphosphane Dioxides With A–π–A–π’–D Scaffolds for High‐Purity Deep‐Blue Luminescence
Diphosphane dioxide‐based luminophores with donor–π–acceptor– π’–acceptor scaffold enable efficient deep‐blue emission from tunable charge‐transfer states affording high photoluminescence up to 95%. OLEDs reach EQE 4.9%, aided by triplet–triplet annihilation, highlighting a practical route to high‐performance blue emitters.
Eetu Hakkarainen +10 more
wiley +1 more source
Temperature dependency of energy shift of excitonic states in a donor–acceptor type TADF molecule
In recent years, thermally activated delayed fluorescence (TADF) has attracted intense attention owing to its straightforward application to high-efficiency organic light-emitting diodes.
Youichi Tsuchiya +7 more
doaj +1 more source
Synthesis and Optical Properties of Diboron Complexes of 1,4‐Anthraquinone Derivatives
1,4‐Diboron complexes exhibit near‐infrared fluorescence, in contrast to non‐emissive 1,5‐diboron analogues. Fluorescence quantum yields decrease with increasing electron‐donating substituents, attributed to enhanced nonradiative decay via intramolecular PeT.
Yasuhiro Kubota +10 more
wiley +1 more source
Reactivity of organic photocatalysts displaying thermally activated delayed fluorescence (TADF): rationalizing unexpected differences between rates of quenching of the lowest singlet and triplet states. [PDF]
Fina F +6 more
europepmc +1 more source
Importance of Selective Quenching of the Triplet Excited State of Thermally Activated Delayed Fluorescence (TADF) Photosensitizers in Redox-Photosensitized Reactions: Case Studies on Photocatalytic CO<sub>2</sub> Reduction. [PDF]
Tamaki Y +4 more
europepmc +1 more source
Study of the thermally-activated delayed fluorescence (TADF) mechanism of phenothiazine-dibenzothiophene-<i>S</i>,<i>S</i>-dioxide electron donor-acceptor dyads using steady-state and time-resolved optical and electron paramagnetic resonance spectroscopies. [PDF]
Pei Y +11 more
europepmc +1 more source
Luminescence thermometry with TADF emitters is only scarcely explored. In this work, photophysical conditions and recommendable read-out strategies for the application of TADF emitters in this application area will be motivated.
openaire +2 more sources
Motivation on Intramolecular Through-Space Charge Transfer for the Realization of Thermally Activated Delayed Fluorescence (TADF)-Thermally Stimulated Delayed Phosphorescence (TSDP) in C^C^N Gold(III) Complexes and Their Applications in Organic Light-Emitting Devices. [PDF]
Li P +8 more
europepmc +1 more source

