A simplified approach to thermally activated delayed fluorescence (TADF) bipolar host polymers [PDF]
Polymer Chemistry, 2022 Herein, we compare a series of solution-processible TADF polymers with different host pendant groups to achieve balanced charge transport properties through the combination of unipolar co-hosts.
Susanna V. Kunz +11 more
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Open questions on the photophysics of thermally activated delayed fluorescence
Communications Chemistry, 2021 The process of thermally activated delayed fluorescence (TADF) converts non-radiative triplet states into emissive singlet states. Herein we outline the fundamentals of TADF, some of the recent progress in understanding the key material properties ...
Julien Eng, Thomas J. Penfold
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Intramolecular Noncovalent Interactions Facilitate Thermally Activated Delayed Fluorescence (TADF)
The Journal of Physical Chemistry Letters, 2019 In the conventional molecular design of thermally activated delayed fluorescence (TADF) organic emitters, simultaneously achieving a fast rate of reverse intersystem crossing (RISC) from the triplet to the singlet manifold and a fast rate of radiative decay is a challenging task.
Xian-Kai Chen +6 more
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Evaluating Multi-Resonant Thermally Activated Delayed (MR-TADF) Fluorescent Compounds as Photocatalysts [PDF]
, 2022 Donor-acceptor (D-A) thermally activated delayed fluorescent (TADF) compounds, such as 4CzIPN, have become a widely used sub-class of organic photocatalysts for a plethora of photocatalytic reactions. Multi-resonant TADF (MR-TADF) compounds, a subclass of TADF emitters that are rigid nanographene derivatives, such as DiKTa and Mes3DiKTa, have to date ...
Callum Prentice +3 more
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Boron-based donor-spiro-acceptor compounds exhibiting thermally activated delayed fluorescence (TADF) [PDF]
Dalton Transactions, 2018 We present highly luminescent borylated 2-phenylpyridines, which exhibit tunable delayed fluorescence due to their donor-spiro-acceptor architecture.
Marco Stanoppi, Andreas Lorbach
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Molecular asymmetry and rigidification as strategies to activate and enhance thermally activated delayed fluorescence in deep-blue MR-TADF emitters [PDF]
Physical Chemistry Chemical PhysicsTwo novel deep-blue multi-resonant thermally activate delayed fluorescnece (MR-TADF) emitters, 1B-CzCrs and 2B-CzCrs, containing a a fused carbazole unit were synthesized. The carbazole contributed to the emergence of TADF in these small molecules. Particularly, organic light-emitting diodes with 1B-CzCrs doped in mCP host achieve a maximum external ...
Rangani Wathsala Weerasinghe +9 more
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Employing organic donor-acceptor thermally activated delayed fluorescence (TADF) compounds as photocatalysts [PDF]
This thesis aims to expand the range of donor-acceptor (D-A) thermally activated delayed fluorescence (TADF) compounds trialled as photocatalysts (PCs), as well as increasing mechanistic understanding of photocatalytic processes. Chapter 1 describes the fundamental photophysical and photochemical processes that underpins the reactivity of the PC.
Bryden, Megan Amy
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Photoactivation-Enabled Tunable Room-Temperature Phosphorescence and Thermally Activated Delayed Fluorescence in Crystalline Materials. [PDF]
Adv Sci (Weinh)This work is the first to demonstrate the regulation of photoactivated room‐temperature phosphorescence (RTP) and thermally activated delayed fluorescence (TADF) in crystalline materials without any pretreatment. Furthermore, we reveal the underlying mechanisms by uncovering the role of host‐guest energy level alignment, exciton lifetime, crystallinity,
Zhang L +5 more
europepmc +2 more sources
Palladium Catalyzed C3-(sp2)-H Alkenylation of Pyrroles: A Direct Access to Novel Organic Thermally Activated Delayed Fluorescence (TADF) Materials [PDF]
, 2023 A Pd (II)-catalyzed direct C3-(sp2)-H alkenylation of heteroarenes using benzothiazole as a directing group has been successfully achieved. A wide range of 2-N-alkylpyrroles undergo an oxidative coupling with a variety of acrylates to furnish highly ...
Anindita , Bhowmick +4 more
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High efficiency blue organic light-emitting diodes with below-bandgap electroluminescence
Nature Communications, 2021 Thermally activated delayed fluorescence organic light-emitting diodes (TADF-OLEDs) rely on high triplet energy interlayers to confine excitons, which results in reduced performance.
Maria Vasilopoulou +17 more
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