Results 121 to 130 of about 98,861 (281)

Cellulosic Biofuels Analysis: Economic Analysis of Alternative Technologies [PDF]

The passage of U.S. laws mandating and subsidizing advanced cellulosic biofuels may spur the development of a commercial cellulosic biofuels industry.
Craig W. Rismiller, Wallace E. Tyner
core  

Solvent‐Driven Pore Engineering in Coffee‐Derived Activated Hydrochar: Implications for Post‐Combustion CO2 Capture

Carbon Energy, EarlyView.
Solvent washing of coffee‐ground hydrochars produces activated carbons with tunable pore sizes while maintaining surface area. Removing non‐polar contaminants enhances microporosity, increasing CO2 uptake by 40%. Moderate pore sizes (9–12 Å) yield optimal CO2:N2 selectivity, whereas smaller pores reduce selectivity due to stronger interactions between ...
Muhammad Irfan Maulana Kusdhany, Maryna Vorokhta, Kazunari Sasaki, Masamichi Nishihara, Stephen Matthew Lyth   +4 more
wiley   +1 more source

THEORY OF HYPERSONIC LAMINAR STAGNATION REGION HEAT TRANSFER IN DISSOCIATING GASES [PDF]

Thermochemical effects of foreign planetary atmospheres upon laminar heat transfer in hypersonic stagnation region - gas ...
Gilbert, L. M., Scala, S. M.
core   +1 more source

Precision Catalysis in Dehydrogenation of Liquid Organic Hydrogen Carriers: Molecular Structure‐Geometry‐Electronic Interplay for Enhanced Hydrogen Evolution

Carbon Energy, EarlyView.
Atomic‐scale design principles for LOHC dehydrogenation: Tailoring geometric and electronic effects in metal catalysts to bridge the molecular structure of LOHC and dehydrogenation performance. ABSTRACT The advancement of hydrogen‐based energy systems necessitates innovative solutions for safe, efficient hydrogen storage and transportation.
Yongxiao Tuo, Jingying Qu, Huailu Sun, Hongwei Gai, Xiangyuan Qu, Junlun Zhu, Xiaohui Sun, De Chen, Xiang Feng   +8 more
wiley   +1 more source

Supramolecular Host‐Guest Complexation Dynamics by Cost‐Efficient Electronic Structure Methods

Chemistry – A European Journal, EarlyView.
We present a cost‐effective multilevel workflow for the kinetic profiling of host–guest systems, illustrated with cucurbit[6]uril and alkylammonium cations. The method combines rapid docking and reaction path searches at the semi‐empirical level, with refinement of the results using modern density functional theory, accurately reproducing experiment ...
Thomas Gasevic, Christoph Plett, Lukas Wittmann, Iago Neira, Carlos Peinador, Marcos D. García, Andreas Hansen   +6 more
wiley   +1 more source

Estimates of thermochemical relaxation lengths behind normal shock waves relevant to manned lunar and Mars return missions, the aeroassist flight experiment, and Mars entry [PDF]

Thermochemical relaxation distances behind the strong normal shock waves associated with vehicles that enter the Earth atmosphere upon returning from a manned lunar or Mars mission are estimated. The relaxation distances for a Mars entry are estimated as
Howe, John T.
core   +1 more source

Photochemistry of Aromatic N‐Oxides in Water Probed by Time‐Resolved X‐ray Absorption Spectroscopy

Chemistry – A European Journal, EarlyView.
Time‐resolved XAS at the nitrogen and oxygen K‐edges is applied to the photorearrangement of two N‐oxides in water. Pyridine N‐oxide rapidly forms the oxaziridine isomer. Pyridazine N‐oxide undergoes ring opening to the diazo compound, without any evidence of intermediates.
Maximilian Paradiz Domínguez, Robby Büchner, Mattis Fondell, Albert M. Brouwer   +3 more
wiley   +1 more source

Multiple Dimerization Modes in Thiocarboxylate Paddlewheel Complexes: A Comprehensive View of Energy Landscapes from DFT Calculations and Statistics

Chemistry – A European Journal, EarlyView.
Staggered, square, and heavily bent dimers occur in the five known solvatomorphs of paddlewheel (PW) complex [PtVO(SOCPh)4]. These and other structural motifs are well within energetic reach due to the shallow potential energy surface that guides dimerization and are included in a revised classification of available structural data on heterobimetallic ...
Olga Mironova, Giacomo Bellini, Alessio Nicolini, Andrea Cornia   +3 more
wiley   +1 more source

Radical Stability Paradox: Substituent Effects versus Heats of Formation

Chemistry – A European Journal, EarlyView.
Rethinking molecular stability: Quantum‐chemical analyses show that the greater stability of tertiary over primary organic radicals is not caused by stabilizing substituent effects but by the inherent stability of the substituent. ABSTRACT Recently, we have shown that alkyl substituents destabilize the carbon radical center of organic radicals. However,
Daniela Rodrigues Silva, Pascal Vermeeren, J. Martijn van der Schuur, F. Matthias Bickelhaupt   +3 more
wiley   +1 more source

Utilization of Waste Materials Using the Müller–Kühne Process—A Life Cycle Inventory Study

Chemie Ingenieur Technik, EarlyView.
This study presents a Life Cycle Inventory of the Müller–Kühne process (MKP), which converts gypsum waste into sulfuric acid and cement clinker. The MKP outperforms conventional cement production regarding material yield, though its specific energy demand is higher. Consequently, potentials for circular gypsum waste utilization are discussed.
Leon Kassner, Manfred Renner, Peter Fröhlich, Martin Bertau, Philip Biessey   +4 more
wiley   +1 more source