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Thermodynamic consistency of kinetic data

Combustion, Explosion, and Shock Waves, 1989
It is well known [1-4] that the rate constants of different elementary reactions are often interdependent. Relationships determined by the principle of detailed balancing exist between them [1-5] when microreversibility is valid and by the generalizations of that principle [5-8] when it is not (for example, in magnetic fields, during macroscopic ...
Gorban', AN   +3 more
openaire   +2 more sources

Methyl orange adsorption comparison on nanoparticles: Isotherm, kinetics, and thermodynamic studies

Dyes and pigments, 2019
A batch equilibrium system has been used to investigate the adsorption of methyl orange (MO) on NiO and CuO nanoparticles (NPs). The effects of experimental conditions such as initial concentration, agitation time, solution pH and temperature were ...
A. Darwish, M. Rashad, Hatem A. Al-Aoh
semanticscholar   +1 more source

Introduction: Thermodynamic Data Systematics

1993
There are different sources of data available for establishing an internally consistent data set: calorimetric measurements, phase equilibrium data, measured thermophysical properties of a phase, and heat capacities and entropies estimated from lattice vibrational models, see, for example, Chopelas (1990a, b), Kieffer (1979a, b, c), Ghose et al. (1992,
Surendra K. Saxena   +3 more
openaire   +1 more source

Thermodynamic data on chalcogenide glasses

Journal of Thermal Analysis, 1976
The temperature-dependence of the specific heat near to the glass temperature was investigated for several Te- and As-based chalcogenide glasses, the latent heats of melting and crystallization of the former alloys also being measured. No thermal change could be detected in the transformation of the As-based alloys from the solid to the liquid state.
J. Hajtó, T. Kemény
openaire   +1 more source

Some mistakes and misinterpretations in the analysis of thermodynamic adsorption data

Journal of Molecular Liquids, 2022
S. Salvestrini, L. Ambrosone, F. Kopinke
semanticscholar   +1 more source

Estimation of Thermodynamic Data

2001
This chapter discusses methods of estimating the standard enthalpy of formation, entropy and heat capacity of molecules and free radicals, using both BENSON’s method and those of statistical mechanics.
openaire   +1 more source

Modelling of Thermodynamic Data

2002
Model building is at best a dynamic process where model fitting and analysis may lead to new experiments and an improved model. The language of statistics is often used for evaluation of models. Statistics, however, is the science of random errors and random errors are not the main problem for model builders.
openaire   +1 more source

Cancer statistics, 2023

Ca-A Cancer Journal for Clinicians, 2023
Rebecca L Siegel   +2 more
exaly  

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