Results 91 to 100 of about 407,104 (336)

In Situ Constructed Magnetic Core‐Shell Hydrogen‐Bonded Organic Framework‐on‐Metal–Organic Framework Structure: an Efficient Catalyst for Peroxymonosulfate Activation

Advanced Functional Materials, EarlyView.
In this work, a magnetic core‐shell catalyst (HOF‐on‐Fe3O4/ZIF‐67) is successfully synthesized, consisting of a metal–organic framework (ZIF‐67) with magnetic Fe3O4 as the core and a porous hydrogen‐bonded organic framework (HOF) as the shell. The catalyst efficiently activated peroxymonosulfate, resulting in rapid and effective removal of water ...
Yingying Du, Chenhui Ding, Chao Deng, Susanta Banerjee, Seema Agarwal   +4 more
wiley   +1 more source

Deciphering the Origin of Higher Shell Coordination on Single Iron Catalysts for Resilient Modulating Persulfate Oxidation Into Singlet Oxygen Pathway

Advanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
This study reveals that higher shell S coordination can effectively modulate the spin state of FeN4 site via long‐range electronic interactions, giving rise to the oriented generation of singlet oxygen from peroxymonosulfate activation. Abstract Precise manipulation of coordination structure of single‐atom sites and establishment of schematic ...
Liang Zhang, Kai Cheng, Zhizhi Yang, Ye Zhang, Shiro Kubuki, Paul A. Bingham, Yang‐Chun Yong, Bofan Zhang, Xiaoguang Duan   +8 more
wiley   +1 more source

Why Should We Use Residual Thermodynamics for Calculation of Hydrate Phase Transitions?

Energies, 2020
The formation of natural gas hydrates during processing and transport of natural has historically been one of the motivations for research on hydrates. In recent years, there has been much focus on the use of hydrate as a phase for compact transport of ...
Bjørn Kvamme, Jinzhou Zhao, Na Wei, Wantong Sun, Mojdeh Zarifi, Navid Saeidi, Shouwei Zhou, Tatiana Kuznetsova, Qingping Li   +8 more
doaj   +1 more source

Ionic Liquid‐Based Reversible Metal Electrodeposition for Adaptive Radiative Thermoregulation Under Extreme Environments

Advanced Functional Materials, EarlyView.
A wideband tunable electrochromic device with dynamic thermal emissivity control is demonstrated. The system enables adaptive heat regulation via electrochemically modulated silver deposition, achieving efficient cooling and heating states. The flexible design ensures mechanical robustness under bending conditions, making it promising for portable and ...
Jiawei Liang, Chenxi Sui, Jiacheng Tian, Genesis Higueros, Ting‐Hsuan Chen, Ronghui Wu, Pei‐Jan Hung, Yang Deng, Natalie Rozman, Willie John Padilla, Po‐Chun Hsu   +10 more
wiley   +1 more source

Most Earth-surface calcites precipitate out of isotopic equilibrium

Nature Communications, 2019
Isotopic thermometry of carbonate minerals postulates that their composition reflects thermodynamic equilibrium constants. Here the authors constrain equilibrium relationships between temperature, 18O/16O and clumped isotopes and find that most natural ...
M. Daëron, R. N. Drysdale, M. Peral, D. Huyghe, D. Blamart, T. B. Coplen, F. Lartaud, G. Zanchetta   +7 more
doaj   +1 more source

Thermodynamic theory of equilibrium fluctuations

Annals of Physics, 2015
The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of non-equilibrium entropy, a fundamental equation of state in the entropy representation, and a fluctuation postulate ...
openaire   +4 more sources

Harnessing Outer Space for Improved Electrocaloric Cooling

Advanced Functional Materials, EarlyView.
A novel radiative heat sink/source‐integrated electrocaloric (R‐iEC) system combines the electrocaloric (EC) effect with a thermally conductive radiative cooler (TCRC) to address heat dissipation limitations in EC devices. Utilizing outer space as a heat sink, the system achieves up to 240 W m−2 of heat dissipation performance, making it highly ...
Dong Hyun Seo, Hyung Rae Kim, Joo Ho Yun, Hyunkyu Kwak, Do Hyeon Kim, Se‐Yeon Heo, Rujun Ma, Gil Ju Lee, Young Min Song   +8 more
wiley   +1 more source

Photoswitchable Conductive Metal–Organic Frameworks

Advanced Functional Materials, EarlyView.
A conductive material where the conductivity can be modulated remotely by irradiation with light is presented. It is based on films of conductive metal–organic framework type Cu3(HHTP)2 with embedded photochromic molecules such as azobenzene, diarylethene, spiropyran, and hexaarylbiimidazole in the pores.
Yidong Liu, Mersad Mostaghimi, Abhinav Chandresh, Saibal Jana, Wolfgang Wenzel, Lars Heinke   +5 more
wiley   +1 more source

Stable and Dendrite‐Free Zinc Metal Anodes Via Interface Nanoarchitectonics for Aqueous Zinc‐Ion Batteries

Advanced Functional Materials, EarlyView.
This review explores Zn anode challenges in aqueous ZIBs, including dendrites, corrosion, and side reactions, and discusses strategies for improvement through Zn anode, electrolyte, and separator modifications to enhance stability and efficiency. Abstract Aqueous rechargeable zinc‐ion batteries (ZIBs) are emerging as promising candidates for next ...
Pragati A. Shinde, Nilesh R. Chodankar, Lok Kumar Shrestha, Amal Al Ghaferi, Ebrahim Alhajri, Katsuhiko Ariga   +5 more
wiley   +1 more source

Optical Control of the Thermal Conductivity in BaTiO3

Advanced Functional Materials, EarlyView.
Light‐driven manipulation of thermal conductivity in archetypal ferroelectric, BaTiO3, offers a novel and effective approach for the dynamical control of the heat flux, with potential applications in thermal management and phonon‐based logic. Abstract Achieving dynamic control over thermal conductivity remains a formidable challenge in condensed matter
Claudio Cazorla, Carlos Escorihuela‐Sayalero, Jesús Carrete, Jorge Íñiguez‐González, Riccardo Rurali   +4 more
wiley   +1 more source