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Thermodynamic Stabilities of Carbocations
2002Publisher Summary This chapter addresses the quantification of the concept of “stability”. Thermodynamic criteria have been applied to rank carbenium ions on the basis of their intrinsic stabilities—that is, stabilities in the absence of solvent. Both experimental and computational data have been used.
José-Luis M. Abboud +4 more
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On the thermodynamic stability of liposomes
Journal of Colloid and Interface Science, 1990Abstract The spontancity of liposome formation and their thermodynamic stability are discussed. It is shown that in general liposomes do not form spontaneously and that some energy input is required to prepare them. This clearly illustrates that their free energy is not the minimum the system can achieve even though they can be made stable for ...
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Thermodynamic Limit and Stability
1999The stability and temperedness conditions (see (2.2.17), (2.2.18)): $$\begin{array}{l}\Phi (\underline q ) = \sum\limits_{i < j} {\varphi ({{\underline q }_i} - {{\underline q }_j}) \ge - BN} \quad stability \\\left| {\varphi (\underline q - \underline {q'} )} \right| \le C{\left| {\underline q - \underline {q'} } \right|^{ - 3 - \varepsilon ...
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Fundamentals of Thermodynamic Stability
2005The second law of thermodynamics states that the entropy change in any spontaneous adiabatic process is greater than or equal to zero. It is a disarmingly simple statement but one that is a cornerstone of scientific theories. It is instrumental in describing the extent and direction of all physical and chemical transformations and contains within it ...
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Irreversible thermodynamic stability criteria
Lettere Al Nuovo Cimento Series 2, 1982B. H. LAVENDA, SANTAMATO, ENRICO
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Thermodynamic Calculation on the Stability of (Fe,Mn)3AlC Carbide in High Aluminum Steels
Journal of Alloys and Compounds, 2010Byeong-Joo Lee +2 more
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