Results 141 to 150 of about 3,492 (235)

Interface Adsorption versus Bulk Micellization of Surfactants: Insights from Molecular Simulations. [PDF]

J Chem Theory Comput
Kanduč M, Stubenrauch C, Miller R, Schneck E.   +3 more
europepmc   +1 more source

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Thermodynamics of micellization of alkylsulphinylalkanols

Transactions of the Faraday Society, 1966
The thermodynamics of micellization of a new series of non-ionic surface-active agents, the alkylsulphinylalkanols (RSO(CH2)nOH), has been examined. It has been shown that the behaviour of methylene groups in close proximity to the hydrophilic groups is very different from those further removed.
J. M. Corkill, J. F. Goodman, P. Robson, J. R. Tate   +3 more
openaire   +2 more sources

Thermodynamics of Micellization from Heat‐Capacity Measurements

ChemPhysChem, 2014
AbstractDifferential scanning calorimetry (DSC), the most important technique for studying the thermodynamics of structural transitions of biological macromolecules, is seldom used in quantitative thermodynamic studies of surfactant micellization/demicellization.
Bojan, Šarac, Marija, Bešter-Rogač, Jurij, Lah   +2 more
openaire   +3 more sources

Thermodynamics of micellization of some zwitterionic N-alkyl betaines

The Journal of Physical Chemistry, 1969
James Swarbrick, J. Daruwala
semanticscholar   +4 more sources

Thermodynamics of Micellization of Multiheaded Single-Chain Cationic Surfactants

Langmuir, 2004
The energetics of micelle formation of three single-chain cationic surfactants bearing single (h = 1), double (h = 2), and triple (h = 3) trimethylammonium [(+)N(CH(3))(3)] headgroups have been investigated by microcalorimetry. The results were compared with the microcalorimetric data obtained from well-known cationic surfactant, cetyl ...
Santanu, Bhattacharya, Jayanta, Haldar
openaire   +3 more sources

Thermodynamics of Micellization of Alkyldimethylbenzylammonium Chlorides in Aqueous Solutions

Journal of Colloid and Interface Science, 2002
Specific conductivities of alkyldimethylbenzylammonium chlorides (alkyl=decyl-, dodecyl-, tetradecyl-, and hexadecyl-) in aqueous solutions were measured as a function of molality and temperature. Critical micelle molalities (cmc) and degrees of ionization of the micelles, beta, were estimated from the dependence of the specific conductivity on ...
Julio R, Rodríguez, Alfredo, González-Pérez, José L, Del Castillo, Jan, Czapkiewicz   +3 more
openaire   +3 more sources

Effect of urea on thermodynamics of micellization

Transactions of the Faraday Society, 1967
The thermodynamic parameters of micellization for two series of surface-active agents have been derived from surface tension and calorimetric measurements in water and urea solutions. Octyl-sulphinylalkanols were used to study the effect of urea on the solvent reorientation associated with the hydrophilic group and alkyltrimethylammonium alkyl ...
J. M. Corkill, J. F. Goodman, S. P. Harrold, J. R. Tate   +3 more
openaire   +2 more sources

Thermodynamics of Micellization of Ionized Surfactants: The Equivalence of Enthalpies of Micellization from Calorimetry and the Variation of Critical Micelle Points with Temperature as Exemplified for Aqueous Solutions of an Aliphatic Cationic Surfactant.

Langmuir, 2021
There is considerable confusion on experimental and thermodynamic aspects of the formation of ionized surfactant micelles. Recent claims that the van't Hoff and calorimetric enthalpies of micellization of ionized surfactants represent different aspects ...
B. McGhee, J. Mingins, B. A. Pethica
semanticscholar   +1 more source

Thermodynamics of micellization of octyltrimethylammonium bromide in 1,2-propanediol-water mixtures at temperatures from (293.15 to 308.15) K

Fluid Phase Equilibria
Carmen M. Romero, Andrea P. Escamilla, Ana C.F. Ribeiro, Miguel A. Esteso   +3 more
openalex   +2 more sources

Thermodynamics of micellization of N-alkyl betaines

Transactions of the Faraday Society, 1965
P. Molyneux, C. T. Rhodes, J. Swarbrick
openaire   +2 more sources