Results 151 to 160 of about 3,492 (235)

Octadecylamine cobalt(III) dimethyl glyoximato complexes: synthesis, thermodynamics of micellization, steady-state photolysis and biological activities

Transition metal chemistry (Weinheim), 2013
S. Caleb Noble Chandar, D. Sangeetha, M. N. Arumugham   +2 more
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Thermodynamics of micellization of n-alkylpyridinium chlorides

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1993
Abstract The effect of temperature on the thermodynamic parameters of micellization of a homologous series of n-alkylpyridinium chlorides has been studied by isothermal microcalorimetry. The decyl, dodecyl and tetradecyl compounds were studied both in water and in 0.1 M NaCl in the temperature range 6–60°C.
Mehrian, T., de Keizer, A., Korteweg, A.J., Lyklema, J.   +3 more
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Thermodynamics of micellization of non-ionic detergents

Transactions of the Faraday Society, 1964
J. M. Corkill, J. F. Goodman, S. P. Harrold   +2 more
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Thermodynamics of mixed micelle formation

Journal of Colloid and Interface Science, 1986
Abstract A new method of calculating the composition of mixed micelles in equilibrium with monomer of known composition is proposed. This technique applies the Gibbs-Duhem equation to be mixed micelle, which is treated as a pseudophase. The method needs only CMC data as a function of monomer composition, but is limited to binary surfactant systems ...
Cuong M Nguyen, James F Rathman, John F Scamehorn   +2 more
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Thermodynamics of anion binding to zwitterionic sulfobetaine micelles

Journal of Colloid and Interface Science, 2022
One of the most intriguing aspects of zwitterionic surfactant micelles is their propensity to exhibit selectivity in the binding of the anions of added salts. In this work we examine the thermodynamics of the interaction of the strongly bound perchlorate ion and the more weakly bound bromide ion with micelles of N-tetradecyl-N,N-dimethyl-3-ammonio-1 ...
Álvaro Javier, Patiño-Agudelo, Frank H, Quina   +1 more
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Analytical modeling of micelle growth. 5. Molecular thermodynamics of micelles from zwitterionic surfactants

Journal of Colloid and Interface Science, 2022
The critical micelle concentration, aggregation number, shape and length of spherocylindrical micelles in solutions of zwitterionic surfactants can be predicted by knowing the molecular parameters and surfactant concentrations. This can be achieved by upgrading the quantitative molecular thermodynamic model with expressions for the electrostatic ...
Krassimir D, Danov, Krastanka G, Marinova, Gergana M, Radulova, Mihail T, Georgiev   +3 more
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Thermodynamics of micelles

Journal of Colloid and Interface Science, 1982
Abstract General equations of the thermodynamics of micellar systems and of a single micelle are given. Relations among the size distribution of micelles, their surface tension, and the CMC are established. An expression for the constant of the law of mass action is obtained in terms of surface tension.
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Thermodynamic stability of worm-like micelle solutions

Soft Matter, 2017
A model is proposed and verified that explains the solution stability of worm-like micelles used in chemotherapy and viscosity enhancement.
Karsten Vogtt, Gregory Beaucage, Michael Weaver, Hanqiu Jiang   +3 more
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Thermodynamic properties of rhamnolipid micellization and adsorption

Colloids and Surfaces B: Biointerfaces, 2014
of the surface tension, density, viscosity and conductivity of aqueous solutions of rhamnolipid at natural and controlled pH were made at 293 K. On the basis of the obtained results the critical micelle concentration of rhamnolipid and its Gibbs surface excess concentration at the water-air interface were determined.
Diana, Mańko, Anna, Zdziennicka, Bronisław, Jańczuk   +2 more
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Thermodynamics of ionic micelles

Russian Chemical Reviews, 1989
The present state of the thermodynamics of ionic micellar systems is examined and the principal characteristics of these systems are discussed: the charge and activity coefficients of the micelles, the concentration of the monomers and the degree of binding of the counterions, and the dependence of the critical micelle formation concentration on the ...
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