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Thermodynamics of ionic surfactant micelle—comments
Journal of Colloid and Interface Science, 1987Abstract The assumptions made in deriving a recently published micellar Gibbs-Duhem equation applicable to micellar solutions of ionic surfactants which may contain several counterion species are stated explicitly and reviewed critically. Possible improvements are suggested.
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Thermodynamics of Micelle Formation of Chlorhexidine Digluconate
The Journal of Physical Chemistry, 1995The critical micelle concentrations (cmcs) of chlorhexidine digluconate (CG) in aqueous solution were determined over the temperature range 15-40 "C by a method based on deconvolution into Gaussians of the second derivative of the conductivity/concentration data. The mass-action model was modified in order to calculate the thermodynamic parameters (Ac",
F. Sarmiento +5 more
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Molecular Thermodynamics of Giant Micelles
2007This chapter summarizes the geometrical relations for spherical, globular, and rodlike micelles, consistent with molecular packing considerations, and develop general thermodynamic equations that govern the formation of rodlike micelles. It shows how to estimate the molecular constants appearing in the free energy expressions, describes the ...
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Thermodynamics of micellization and oil solubilization in block copolymers P85
Journal of Thermal Analysis and Calorimetry, 2022M. Basu +3 more
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Molecular-Thermodynamic Theory of Micellization of pH-Sensitive Surfactants
Langmuir, 2006A predictive, molecular-thermodynamic theory is developed to model the micellization of pH-sensitive surfactants. The theory combines a molecular-thermodynamic description of micellization in binary surfactant mixtures with the protonation equilibrium of the surfactant monomers.
Arthur, Goldsipe, Daniel, Blankschtein
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Thermodynamics of hexadecyltrimethylammonium bromide micelle formation
Russian Journal of Physical Chemistry A, 2017The thermodynamic parameters for CTAB micelle formation (ΔН, ΔG, ΔS) are calculated at different temperatures. Critical micelle concentrations CMC1 are determined. The possibility of determining CMC2 is demonstrated.
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Thermodynamics of mixed micelles: Determination of the aggregate composition
Journal of Colloid and Interface Science, 2008In most studies concerning surfactant mixtures, the determination of the composition of mixed micelles is often tricky. This composition can be obtained by different ways. One of them, undoubtedly the most used, supposes, a priori, that the surfactant in the micelle follows the regular solution model.
Pierre, Letellier +2 more
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Fluid Phase Equilibria, 2012
Abstract Measurements of density, viscosity, conductivity and light scattering of aqueous solutions of sodium dodecylsulfate (SDDS), sodium hexadecylsulfonate (SHS), sodium N-lauryl sarcosinate (SDSa), cetyltrimethylammonium bromide (CTAB), cetylpyridinium bromide (CPyB), dodecyldimethyethylammonium bromide (DDEAB), tetradecyltrimethylammonium ...
Anna Zdziennicka +3 more
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Abstract Measurements of density, viscosity, conductivity and light scattering of aqueous solutions of sodium dodecylsulfate (SDDS), sodium hexadecylsulfonate (SHS), sodium N-lauryl sarcosinate (SDSa), cetyltrimethylammonium bromide (CTAB), cetylpyridinium bromide (CPyB), dodecyldimethyethylammonium bromide (DDEAB), tetradecyltrimethylammonium ...
Anna Zdziennicka +3 more
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