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Journal of Colloid and Interface Science, 2020
Vivian J. Spiering +2 more
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Vivian J. Spiering +2 more
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Thermodynamics of Solubilization Into Surfactant Micelles
1990Solubilization into surfactant micelles is examined from the viewpoint of the phase rule. Treating micelles as a separate phase, into which bulk phase solubilizate can partition, turns out to be inconsistent with the rule. On the contrary, the treatment of micelles as chemical species can perfectly elucidate solubilization in a manner consistent with ...
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Langmuir
In this paper, we proposed a thermodynamic procedure to evaluate binary surfactant mixed adsorbed film and mixed micelle compositions above critical micelle concentrations. This theory first calculates the change in the molar ratio of two surfactants in monomer and micelle states based on the phase-separation model and then imposes the chemical ...
Hiroki Matsubara +3 more
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In this paper, we proposed a thermodynamic procedure to evaluate binary surfactant mixed adsorbed film and mixed micelle compositions above critical micelle concentrations. This theory first calculates the change in the molar ratio of two surfactants in monomer and micelle states based on the phase-separation model and then imposes the chemical ...
Hiroki Matsubara +3 more
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Thermodynamic anatomy of micelle-small molecule coacervation
Soft MatterWater-expulsion entropy drives micelle-small molecule coacervation despite an overall enthalpic penalty from ion–water interactions.
Fengxiang Zhou +2 more
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, 2021