A Simple Micellar Gold Catalyst Supported by a Hydrophilic Phosphinoferrocene Amidosulfonate Ligand
A phosphinoferrocene amidosulfonate and its chlorogold complex form micelles in water. The complex can be used as a self‐activating Au catalyst, as demonstrated for the model cyclization of N‐propargyl benzamide into 4,5‐dihydro‐5‐methylene‐2‐phenyloxazole.
David Rezazgui +3 more
wiley +1 more source
Comparing open and closed molecular self-assembly [PDF]
We study theoretically in the present work the self-assembly of molecules in an open system, which is fed by monomers and depleted in partial or complete clusters. Such a scenario is likely to occur for example in the context of viral self-assembly.
Castelnovo, Martin +2 more
core +6 more sources
Ultrathin Mesoporous Metal‐Organic Framework Nanosheets
A bottom‐up interface‐directed co‐assembly strategy enables the synthesis of ultrathin 2D mesoporous UiO‐66(Ce) nanosheets with tunable thickness and uniform mesopores. The enhanced mass transport and accessible active sites significantly improve performance, highlighting the synergistic effects of 2D morphology and mesopores in metal‐organic ...
Yingji Zhao +12 more
wiley +1 more source
Two‐Phase Epoxidations with Micellar Catalysts: Insights, Limitations, and Perspectives
Biphasic phase‐transfer catalysis is a promising strategy for catalyst recycling, which has successfully been applied to various industrial‐scale reactions. Its extension to oxidation reactions is, however, challenging. This concept article discusses epoxidations in water using surface‐active catalysts and emphasizes potential pathways toward more ...
Markus Hegelmann, Mirza Cokoja
wiley +1 more source
Free Radical Entry in Emulsion Polymerization: A Comprehensive Theory
Contrary to previous theories on free radical entry, most of the initiator‐derived radicals can enter the particles. Their contribution to the total entry rate can vary depending on a balance between thermodynamic and kinetic factors where electrostatic repulsion plays an important role which accentuates the diffusive control of the entry process ...
Jorge Herrera‐Ordonez
wiley +1 more source
Micellization thermodynamics as a function of the temperature of a cationic zwitterionic dodecyl phosphocholine and anionic sodium dodecyl sulfate mixed micelles with fluorometry [PDF]
Raghda Abou Gabal +3 more
openalex +1 more source
Micellization in a Mixed Alkali Soap System [PDF]
The solubility of sodium octanoate and sodium dodecyl sulphate (SDS) in the micelle was investigated by measuring the surface tension of the aqueous solution of surfactant mixture as a function of mole fraction of surfactants. Results indicate that the
Che Rose, Laili +2 more
core
Carbohydrate-derived surfactants containing an N-Acylated amine functionality : fundamental aspects and practical applications [PDF]
Surfactants (a contraction of the term surface active agents) are large volume chemicals; their annual production exceeds 5 million tons worldwide. They are primarily used as cleaning agents in laundry and dish-washing applications.
Pestman, Jolanda Monique,
core +2 more sources
This article has been published in an open access journal and is also available at http://www.benthamscience.com/open/totherj/articles/V002/13TOTHERJ.pdfInternational audienceThe Scott-Magat polymer theory, which assumes that polymers have heterogeneous ...
Mohammadi, Amir H., Richon, Dominique
core +1 more source
Interaction of acridine orange with bile salts: a spectroscopic approach [PDF]
Acridine orange (AO) is a metachromic cationic dye and its photophysical property is extremely sensitive to its environment and surrounding pH conditions.
Subadini , Suchismita
core

