Results 41 to 50 of about 28,387 (252)

Polarizable Vanadium Dipoles Promote Water Dissociation on Vanadium‐Based Metal Organic Framework

open access: yesAdvanced Functional Materials, EarlyView.
The polarization of unpaired V 3d electrons weakens the H─O bond to improve water dissociation by the dual Vδ+:O─H and Pλ−:H─O coupling hydrogen bonds formation and relaxation. P@V‐MOF electrocatalyst shows low overpotentials (94 mV in acid, 178 mV in neutral, and 77 mV in alkaline solutions) with excellent stability for effective overall water ...
Xinjuan Liu   +13 more
wiley   +1 more source

Thermogravimetry–differential thermogravimetry (TG-DTG) and differential scanning calorimetry (DSC) analysis of β-cyclodextrin/common bean lipid fraction complexes.

open access: yes, 2019
Thermogravimetry–differential thermogravimetry (TG-DTG) and differential scanning calorimetry (DSC) analysis of β-cyclodextrin/common bean lipid fraction complexes.
Laura Rădulescu (7961645)   +10 more
core   +1 more source

Water‐Compatible SuFEx‐Active Diazonium Linchpin Platform for Rapid Modular Diversification and On‐DNA Functionalization

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur fluoride exchange (SuFEx) is a powerful click platform, yet water‐compatible multifunctional linchpins remain elusive. Here, we report decagram‐scalable diazonium linchpins that enable rapid Pd‐catalyzed diversification and direct, catalyst‐free on‐DNA ligation in aqueous media.
Seok Ju Hong   +5 more
wiley   +1 more source

Gel-combustion synthesis of CoSb2O6 and its reduction to powdery Sb2Co alloy [PDF]

open access: yesJournal of the Serbian Chemical Society, 2009
Sb2Co alloy in powdery form was synthesized via reduction with gaseous hydrogen of the oxide CoSb2O6, obtained by the citrate gel-combustion technique. The precursor was an aqueous solution of antimony nitrate, cobalt nitrate and citric acid.
Jović Maja   +4 more
doaj   +1 more source

Vacuum versus ambient pressure inert gas thermogravimetry: a study of silver carboxylates

open access: yes, 2022
A comparative study of vacuum versus ambient pressure inert gas thermogravimetry was performed on silver carboxylates compounds. Some of the complexes from this group have been previously successfully applied as precursors for both chemical vapour ...
Jurczyk, Jakub   +8 more
core   +1 more source

Bio‐Inspired Synthesis of Macroporous Single Crystal Particles as Scattering Agents

open access: yesAdvanced Functional Materials, EarlyView.
A general strategy is presented that delivers unique, single‐crystal microparticles that combine submicron macroporosity and uniform particle shapes. A bioinspired approach is used to occlude three distinct types of additives – polystyrene microspheres, polymer vesicles and amino acids – within calcite single crystals, and subsequent thermal annealing ...
Stephanie E. Foster   +11 more
wiley   +1 more source

Continuous Thermogravimetry under Cyclic Conditions [PDF]

open access: yes, 2004
Thermogravimetry during cyclic oxidation of metallic alloys is described. A methodology is given in order to determine the Net Mass Gain, the GrossMass Gain, the total mass of spalled oxide, the rate of metal consumption and the average oxide scale ...
Poquillon, Dominique, Monceau, Daniel
core   +1 more source

Semiconducting Polymers Post‐Functionalized With Ureido‐Pyrimidinone for Robust Stretchable Transistors

open access: yesAdvanced Functional Materials, EarlyView.
The design of intrinsically robust stretchable semiconducting polymers was achieved through OTBS‐mediated post‐functionalization of PDPP2T side chains with UPy units, generating dual hydrogen‐bonding motifs comprising weaker urethane linkages and strong quadruple UPy interactions along the long alkyl side chain, which is crucial for achieving desirable
Dinda Bazliah   +7 more
wiley   +1 more source

Biomineral‐Inspired Organic/Inorganic Colloidal Liquid‐Crystalline Hybrids for Photoresponsive Adhesion

open access: yesAdvanced Functional Materials, EarlyView.
A new class of photoresponsive liquid‐crystalline (LC) adhesives based on biomineral‐inspired organic/inorganic colloidal hybrids is reported. These colloidal LC materials are formed by hybridization of a hydroxyapatite nanorod with azobenzene‐based forklike molecules.
Junya Uchida   +4 more
wiley   +1 more source

Electrostatic Superlattices Beyond 1:1 Stoichiometry

open access: yesAdvanced Functional Materials, EarlyView.
Polymer‐mediated charge regulation drives two hierarchical routes to higher‐stoichiometry nanoparticle superlattices. Tuning the polymer's molecular weight promotes progressive interstitial filling, transforming ZnS into the fully occupied CaF2${\rm CaF}_2$ lattice. Exchanging polymer assignment between large and small nanoparticles instead breaks CsCl
Binay P. Nayak   +7 more
wiley   +1 more source

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