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Thermoresponsive copolymer microgels
Journal of Materials Chemistry B, 2013Colloidal aqueous microgels have attracted notable attention due to their possible applications in both polymer chemistry and the (bio)material sector. Due to their soft internal network structure and their response to different external stimuli, they are suitable as carrier systems for different kinds of molecules (e.g.
Hertle, Yvonne, Hellweg, Thomas
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Hollow Thermoresponsive Microgels
Small, 2005AbstractThermoresponsive poly(N‐isopropyl acrylamide) (pNIPAm) microgels possessing a hollow structure have been synthesized from core–shell nanoparticles upon oxidation of the particle core, followed by removal of the produced polymer segments by centrifugation.
Satish, Nayak +3 more
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Thermoresponsive Gold Nanoparticles with Positive UCST‐Type Thermoresponsivity
Macromolecular Chemistry and Physics, 2014Trithiocarbonate end‐functionalized poly(N‐acryloylglycinamide) (PNAGA), synthesized via reversible addition–fragmentation transfer (RAFT) polymerization of different molecular weights, is grafted onto gold nanoparticles (AuNPs) by ligand exchange in phosphate‐buffered saline.
Fangyao Liu, Seema Agarwal
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Thermoresponsive chiral plasmonic nanoparticles
Nanoscale, 2022Poly(N-isopropylacrylamide) (PNIPAM) has been used to modify chiral plasmonic nanoparticles. The thermoresponsive studies reveal the impact of achiral dielectric nanoenvironment on chiral plasmonic responses.
Yiyi Liu +10 more
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European Journal of Organic Chemistry, 2017
We demonstrate herein that corannulene, a bowl‐shaped polycyclic aromatic hydrocarbon, can assemble into larger supramolecular structures in water through a change in the solution temperature. This property is invoked through a simple five‐fold symmetric substitution of the corannulene nucleus with triethylene glycol units.
Surendra H. Mahadevegowda +1 more
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We demonstrate herein that corannulene, a bowl‐shaped polycyclic aromatic hydrocarbon, can assemble into larger supramolecular structures in water through a change in the solution temperature. This property is invoked through a simple five‐fold symmetric substitution of the corannulene nucleus with triethylene glycol units.
Surendra H. Mahadevegowda +1 more
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Thermoresponsive dendritic oligoethylene glycols
Physical Chemistry Chemical Physics, 2022Dendritic oligoethylene glycols show topological structure-dependent thermoresponsiveness to intriguingly encapsulate guests and there is a balance between the dehydrated and the hydrated molecules at elevated temperatures.
Gang Xu +5 more
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Backbone-Thermoresponsive Hyperbranched Polyethers
Journal of the American Chemical Society, 2006A new type of materials, the backbone-thermoresponsive hyperbranched polyether, was successfully synthesized by proton-transfer polymerization of 1,4-butanediol diglycidyl ether and various triols, and the lower critical solution temperature (LCST) values can be readily adjusted from 19.0 to 40.3 degrees C by changing the hydrophilic/hydrophobic ...
Zhifeng, Jia +3 more
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Thermoresponsive Hydrogels for Cellular Delivery
Therapeutic Delivery, 2012The delivery of living cells into a host body has emerged as a promising approach to treating a variety of different diseases and for tissue repair. However, one of the major obstacles for clinical success is to deliver the cells to the target tissue without losing control of cell fate and function after transplantation.
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Engineering thermoresponsive polymeric nanoshells
Biomaterials, 2009This study describes a family of hollow nanoscale constructs able to display a large and reversible change in size, within a narrow temperature interval. These thermoresponsive nanostructures are generated by crosslinking functionalized amphiphilic molecules, such as poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO ...
Daniel, Cohn +3 more
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Thermoresponsive Supramolecular Dendronized Polymers
Chemistry – An Asian Journal, 2011AbstractCombining the concepts of supramolecular polymers and dendronized polymers provides the opportunity to create bulky polymers with easy structural modification and tunable properties. In the present work, a novel class of side‐chain supramolecular dendronized polymethacrylates is prepared through the host–guest interaction.
Jiatao, Yan +6 more
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