Crucial Role of Oxidation for the Prebiotic Peptide Elongation Promoted by Carbonyl Sulfide
The prebiotic activation of amino acid (AA) into peptides via N‐carboxyanhydride (NCA), promoted by carbonyl sulfide (COS), cannot proceed without an oxidizing step (enabling better leaving groups than sulfur dianion). While being efficient even at mild pH the prebiotic scope of COS promoted activation of AA, it is however limited because side ...
Alexandre Desfoux +4 more
wiley +1 more source
Cloning and characterization of herbicide-degrading glutathione transferases from cicer arietinum [PDF]
GSTs are multifunctional enzymes that catalyze the conjugation of glutathione (GSH) to reactive electrophiles. These electrophiles are diverse and include important endogenous compounds, as well as xenobiotic chemicals, therefore GSTs play an important ...
Kontouri, Kassiani G. +1 more
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NAD(P)H:quinone oxidoreductase 1 inducer activity of some novel anilinoquinazoline derivatives [PDF]
The Kelch-like ECH-associated protein 1 (Keap1)/nuclear factor erythroid 2-related factor 2 (Nrf2)/antioxidant response elements pathway enables cells to survive oxidative stress conditions through regulating the expression of cytoprotective enzymes such
Alsaid, Mansour S +6 more
core +3 more sources
Objectives Growing evidence suggests farming and agricultural pesticide use may be associated with rheumatoid arthritis (RA), but few studies have examined specific pesticides and RA among women living on farms, who may personally use pesticides or may be indirectly exposed.
Christine G. Parks +7 more
wiley +1 more source
A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ2 S,S′]zinc(II)]-μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3 S,S′:N] 4-methylpyridine hemisolvate] [PDF]
The title compound, {[Zn(C9H11N2S2)2]·0.5C6H7N} n , comprises two independent, but chemically similar, Zn[S2CN(Et)CH2py]2 residues and a 4-methylpyridine solvent molecule in the asymmetric unit.
Arman, Hadi D. +2 more
core +1 more source
ABSTRACT The presence of pesticide residues in food crops poses serious health concerns, necessitating precise, rapid and accessible detection techniques. This study investigates the use of Raman spectroscopy combined with advanced data analysis techniques to detect and quantify Mancozeb residues in collard greens. The primary objective was to evaluate
Saaya Abel Kanai +3 more
wiley +1 more source
Effects of Metolachlor, Oxyfluorfen and Picloram on Cellulose Decomposition in a Peat Soil under Laboratory Conditions [PDF]
The effects of the three herbicides, metolachlor, picloram and oxyfluorfen on cellulose decomposition were studied in a peat soil in laboratory experiments.
A., Ramli, Sahid, Ismail, Z., Razali
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Synthesis of positively and negatively charged silver nanoparticles and their deposition on the surface of titanium [PDF]
Bacterial infections related to dental implants are currently a significant complication. A good way to overcome this challenge is functionalization of implant surface with Ag nanoparticles (NPs) as antibacterial agent.
Epple, M. +5 more
core +1 more source
Deuteration of Six‐Membered N‐Heteroarenes: Chemistry and Applications
Deuterated six‐membered N‐Heteroarenes (6NHetAr) are finding utility in an increasing repertoire of applications. Our paper comprehensively reviews synthetic approaches that have been reported for the deuteration of 6NHetAr and their fused counterparts while providing an overview of established and emerging applications for these materials.
Liju Raju +4 more
wiley +1 more source
Synthesis of N-Fmoc-ProtectedAmino Alkyl Thiocyanates/Selenocyanates and their Applicationin the Preparation of 5-Substituted S/Se-Linked Tetrazoles [PDF]
A novel class of N-Fmoc-protected amino alkyl thiocy- anates/selenocyanates has been prepared by thiocyanation/seleno-cyanation of the corresponding alkyl iodides. These thiocyanates/selenocyanates undergo a facile [2+3]-cycloaddition reaction
Basavalingappa, P. Vasantha +2 more
core +1 more source

