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Gold Thione Complexes [PDF]

open access: yesInorganics, 2014
The reaction of the ligand Et4todit (4,5,6,7-Tetrathiocino-[1,2-b:3,4-b']-diimidazolyl-1,3,8,10-tetraethyl-2,9-dithione) with gold complexes leads to the dinuclear gold(I) complexes [{Au(C6F5)}2(Et4todit)] and [Au(Et4todit)]2(OTf)2, which do not contain ...
Francesco Caddeo   +5 more
doaj   +7 more sources

Crystal structure of [μ2-1,1′-bis(diphenylphosphanyl)ferrocene-κ2P:P′]bis[(pyrrolidine-1-carbodithioato-κS)gold(I)] [PDF]

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The asymmetric unit of the title compound, {(C34H28FeP2)[Au(C5H8NS2)]2}, comprises half a molecule, with the full molecule being generated by the application of a centre of inversion.
Yee Seng Tan, Edward R. T. Tiekink
doaj   +3 more sources

1-Vinyl-4-imidazoline-2-thione

open access: yesIUCrData, 2017
The title compound, C5H6N2S, was obtained by deprotonation of 1-vinylimidazole and subsequent reaction with elemental sulfur. In the crystal, the molecules are linked by N—H...S and C—H...S hydrogen bonds, and arranged in layers parallel to the ab plane.
Martin Lampl   +4 more
doaj   +2 more sources

Photochemical Hydroxyl Group Abstraction from N-Hydroxypyridine-2(1H)-thione Isolated in a Solid Hydrogen Matrix: Photogeneration of 2-Mercaptopyridine [PDF]

open access: yesMolecules
Monomers of N-hydroxypyridine-2(1H)-thione were isolated in low-temperature matrices of solid normal hydrogen (n-H2). The matrix-isolated compound was irradiated with UV-B (λ = 305 nm) or UV-A (λ > 360 nm) light.
Hanna Rostkowska   +3 more
doaj   +2 more sources

4,5-Diferrocenyl-1,2-dithiole-3-thione

open access: yesIUCrData, 2022
The structure of 4,5-diferrocenyl-1,2-dithiole-3-thione, [Fe2(C5H5)2(C13H8S3)] or C23H18Fe2S3, at 130 K has monoclinic (P21/c) symmetry. The molecule has two ferrocenyl units attached to a 1,2-dithiole-3-thione moiety.
Jessica J. Sánchez-García   +3 more
doaj   +3 more sources

Pyrazine-2(1H)-thione [PDF]

open access: yesIUCrData, 2021
The title compound, C4H4N2S, was obtained by the reduction of 2-mercaptopyrazine (during its crystallization with 2-mercaptopyrazine and isonicotinic acid N-oxide in ethanol solution. It crystallizes in the monoclinic space group P21/m. In the crystal, the molecules are linked by N—H...N and C—H...S hydrogen bonds.
Adrian Olszewski, Kinga Wzgarda-Raj
openaire   +5 more sources

Complex formation of molybdenum (V) with 1-phenyl-2,3-dimethylpyrazoline-5-thion in 4 mol/L HCI medium at 273-338 K [PDF]

open access: yesE3S Web of Conferences, 2023
The process of complexation of molybdenum (V) with 1-phenyl-2,3-dimethylpyrazolin-5-thione in a 4 mol/l HCI medium in the temperature range 273-338 K was studied by the potentiometric method.
Egamberdiev A. Sh.   +4 more
doaj   +1 more source

Synthesis of racemic and chiral BEDT-TTF derivatives possessing hydroxy groups and their achiral and chiral charge transfer complexes [PDF]

open access: yes, 2015
Chiral molecular crystals built up by chiral molecules without inversion centers have attracted much interest owing to their versatile functionalities related to optical, magnetic, and electrical properties.
Hashimoto, C   +6 more
core   +11 more sources

Synthesis of Catena-bis(μ-bromo)-(O-methyl-N-phenylthiocarbamate)-dicopper(I) and Its Reactivity towards PAr3 (Ar = Ph, p-Tol)

open access: yesMolbank, 2023
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands toward coinage metals, CuBr was reacted with one equivalent of MeOC(=S)N(H)Ph L in MeCN solution to afford the 1D-polymeric title compound [{Cu(μ2-Br)2Cu}{μ2-MeOC(=
Wafa Arar   +6 more
doaj   +1 more source

Synthesis and characterization of mercury(II) mixed ligands complexes derived from 5-(4-pyridyl)-1,3,4-oxadiazole-2-thione with tertiary phosphines ligands [PDF]

open access: yesKirkuk Journal of Science, 2017
Many new mixed ligand mercury complexes have been synthesized with LH = 5(4-pyridyl)-1,3,4-oxadiazole-2-thione and tertiary phosphines as co-ligands.
and Shihab A. O. Ahmed   +2 more
doaj   +1 more source

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