Results 91 to 100 of about 27,016 (208)
[2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties
The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite.
Laura G. Sarbu +4 more
doaj +1 more source
Novel applications of the "t-amino effect" in heterocyclic chemistry. Synthesis of a pyrrolo[1,2-a]quinazoline and 5H-pyrrolo[1,2-a][3,1]benzothiazines [PDF]
1-(1-Pyrrolidinyl)benzenes substituted with an imino- or an in situ generated thiocarbonyl group in the 2-position rearrange upon heating to quinazoline and benzothiazine derivatives ...
Hamzink, M.R.J. +3 more
core +3 more sources
A divergent halogen‐promoted intramolecular sulfenylation of dienamines enables access to two unprecedented families of benzo[4,5]imidazo[2,1‐b]thiazole. The resulting scaffolds feature distinct chiral elements, either a quaternary stereocenter in the case of spirolactones, or a stereogenic axis for heteroaryl‐alkenes, with high configurational ...
Charlou Rognan +5 more
wiley +1 more source
Tautomeric Equilibria Studies by Mass Spectrometry [PDF]
Tautomerism in organic chemistry has been extensively studied in condensed phase by spectrometric methods, mainly by IR and NMR techniques. Mass spectrometry studies start 40 years ago but just recently it has been recognized the importance of the mass ...
Eduardo A. Castro +3 more
core +1 more source
Biologically active thiosemicarbazone Fe chelators and their reactions with ferrioxamine B and ferric EDTA; a kinetic study [PDF]
The Fe abstraction from Fe /DFO and Fe /EDTA complex systems by thiosemicarbazone ligands derived from 2-acetylpyridine has been studied from a kinetico-mechanistic perspective at relevant pH conditions and at varying temperatures and buffer solutions ...
Bernhardt, Paul V. +3 more
core +1 more source
Gold–Thiopurine and Thioguanine Platforms for Chemotherapy and Photodynamic Therapy
Gold(I)–thiopurine complexes bearing chromophores and phosphine or N‐heterocyclic carbene ligands were developed as multimodal chemo‐photodynamic agents. They show good stability, moderate lipophilicity, and tunable photoresponse. 6‐TG enhances dark cytotoxicity, 6‐MP improves phototoxicity, and PPh3/NBD provide the most efficient photoactivation ...
Laura Agulló +3 more
wiley +1 more source
Summary Temperature influences the distribution and performance of both plants and insect herbivores. Consequently, plant–herbivore interactions are likely to vary across thermal gradients, which could affect the evolution of plant defense. Furthermore, temperature fluctuations may elicit immediate changes in defense.
Thomas Dorey +5 more
wiley +1 more source
Thione-thiol tautomerism of thiourea ligands on silica surface
Quantum chemical calculations of the IR spectra of the thione and thiol forms of N, N'-dimethylthiourea and silica surface fragment with composition (HO)3SiCH2NHC(S)NHCH3 (density functional theory method, B3LYP/6-31G (d, p)) make it possible to fix ...
O. V. Smirnova +3 more
doaj +1 more source
O-Methyl m-Tolylcarbamothioate
The synthesis, spectroscopic, and crystallographic characterisation of the title compound, O-methyl m-tolylcarbamothioate, MeOC(=S)N(H)(m-tolyl) (1), are described.
Chien Ing Yeo, Edward R. T. Tiekink
doaj +1 more source
A Non-Covalent Antibody Complex for the Delivery of anti-cancer drugs [PDF]
Antibody drug conjugates (ADCs), which are obtained by coupling a potent cytotoxic agent to a monoclonal antibody (mAb), are traditionally bound in a random way to lysine or cysteine residues, with the final product's heterogeneity having an important ...
Grigoletto, Antonella +5 more
core +1 more source

