Results 11 to 20 of about 27,016 (208)

Perhydrobenzimidazole-2-thione [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2009
The studied crystal of the title compound, C(7)H(12)N(2)S, is a racemic mixture of two isomers, viz. S,S and R,R. The two isomers share the same position on a mirror plane in the space group P2(1)/m; thus all atoms except one are disordered between two positions in a 1:1 ratio.
XiaoYu Li, YingChun Liu
openaire   +3 more sources

Bis(μ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth

open access: yesMolbank, 2022
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, BiI3 was reacted with two equivalents of MeOC(=S)N(H)Ph in MeCN solution to afford the dinuclear title compound complexes [{I2Bi(μ2-I)2BiI2}{κ1-MeOC(=S)N(H)Ph}4 ...
Wafa Arar   +4 more
doaj   +1 more source

1,3-Dibenzylimidazolidine-2-thione [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2012
In the title compound, C17H18N2S, the imidazolidine ring adopts a twisted conformation. In the crystal, molecules are linked by slipped π–π interactions between the benzene rings of neighbouring molecules [centroid-to-centroid distance = 3.903 (2) Å].
Anna Mietlarek-Kropidłowska   +2 more
openaire   +3 more sources

Synthesis and characterization of Pd(II) and Pt(II) complexes containing mixed ligands of thione and diamine

open access: yesTikrit Journal of Pure Science, 2023
New Pd(II) and Pt(II)  complexes of the type [M(bzoS)2(diamine)] {where M = Pd(II) or Pt(II) } from the treatment of one mole of the diamine ligands {diamine = , phenanthroline (Phen), bipyridine (Bipy), ethylene diamine (en), or N,N′-dimethyl ethylene ...
Ahmed S. M. Al-Janabi
doaj   +1 more source

Synthesis of Thiazole-2(3H)-thiones as Antimicrobial Agents Promoted by H3PW12O40-amino-functionalized CdFe12O19@SiO2 Nanocomposite [PDF]

open access: yesNanochemistry Research, 2022
H3PW12O40-amino-functionalized CdFe12O19@SiO2 nanocomposite has been utilized as an effective nanocatalyst for the preparation of thiazole-2(3H)-thiones by three-component reactions of CS2, 2-bromoacetophenone or 2-bromo-1-(4-methoxyphenyl) ethenone, and
Hossein Shahbazi-Alavi   +1 more
doaj   +1 more source

Thione photochemistry. Dual pathways in aralkyl thione cyclizations [PDF]

open access: yesCanadian Journal of Chemistry, 1981
It is shown that aralkyl thiones, which possess an oxygen atom at the δ position in the side chain, can therefore not undergo the preferred δ insertion, and insert at the γ and ε positions. Although ε insertion occurs only from the 1(π,π*) state, γ abstraction (followed by cyclization or cleavage) occurs from both 1(π,π*) and 3(n,π*) states.
S. Basu   +5 more
openaire   +1 more source

Metal–Dithiolene Bonding Contributions to Pyranopterin Molybdenum Enzyme Reactivity

open access: yesInorganics, 2020
Here we highlight past work on metal−dithiolene interactions and how the unique electronic structure of the metal−dithiolene unit contributes to both the oxidative and reductive half reactions in pyranopterin molybdenum and tungsten enzymes ...
Jing Yang   +2 more
doaj   +1 more source

Synthesis and structures of dinuclear palladium complexes with 1,3-benzimidazolidine-2-thione and 1,3-imidazoline-2-thione

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2023
The synthesis and structures of dinuclear palladium complexes with 1,3-benzimidazolidine-2-thione (bzimtH) and 1,3-imidazoline-2-thione (imtH) are reported, namely, bis(μ-1H-benzimidazole-2-thiolato)-κ2N3:S;κ2S:N3-bis[cyanido(triphenylphosphine-κP ...
Tarlok S. Lobana   +5 more
doaj   +1 more source

Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts [PDF]

open access: yes, 2013
The syntheses of a range of enantiopure organosulfur donors with hydrogen bonding groups are described including TTF related materials with two, four, six and eight hydroxyl groups and multiple stereogenic centres and a pair of chiral N-substituted BEDT ...
Akutsu, H   +11 more
core   +1 more source

Synthetic strategies for preparing BEDT-TTF derivatives functionalised with metal ion binding groups [PDF]

open access: yes, 2006
The syntheses of BEDT-TTF (ET) derivatives with potential metal ion binding pyridyl, bipyridyl and terpyridyl groups are achieved either by stepwise construction of the organosulfur core or via reactions of hydroxymethyl-ET for which a cheap and ...
Alberola   +60 more
core   +1 more source

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