Results 131 to 140 of about 3,220 (257)

Size Matters: Barrier Heights and Widths in the Kinetics Of Tautomerisation and Rotamerisation of Thiotropolone and Its Five‐ and Three‐Membered Cyclic Analogues

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT Recent experiments by Nunes et al. have demonstrated that unprecedented control of chemical reactions is possible by narrowband infrared vibrational photo‐excitation at low temperatures in inert matrices. The generated higher energy level conformers may then undergo rotamerisation and tautomerisation reactions which provide extremely useful ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Exometabolomics Reveals Metabolic Modulation Induced by Chia Oil Supplementation in Adipose Tissue Explants From Obese Mice

open access: yesLipids, EarlyView.
The experimental design and the exometabolomic findings obtained by 1H‐NMR analysis of conditioned media from subcutaneous (SAT) and epididymal adipose tissue (EAT) explants of control and obese mice supplemented with chia oil (1.5% (w/w)). Following 8 weeks of control or high‐fat diet and 5 weeks of chia oil supplementation, SAT and EAT explants were ...
Gilson Costa dos Santos Jr   +5 more
wiley   +1 more source

Optically Bound Rapid Plasmonic Nanorod Dimers: Anisotropic Dynamics Driven by Light‐Fluidic Cooperation

open access: yesLaser &Photonics Reviews, EarlyView.
Optically confined gold nanorods exhibit cooperative light‐driven dynamics, forming mobile end‐to‐end dimers with orientation‐dependent propulsion. Using structured laser traps and an opto‐thermo‐hydrodynamic model, we uncover how optical binding, polarization‐induced torque, and near‐surface hydrodynamics govern their motion.
José A. Rodrigo, Tatiana Alieva
wiley   +1 more source

Static and Dynamic Analysis of Porous Gas Bearings Lubricated With Air, Refrigerant R‐134a, Helium and Hydrogen

open access: yesLubrication Science, EarlyView.
ABSTRACT Porous gas bearings (PGBs) enable high‐speed, oil‐free operation in modern rotating machinery. This study develops a coupled thermo‐hydrodynamic (THD) model for a cylindrical porous gas bearing lubricated with four working fluids—air, R‐134a, helium and hydrogen.
S. Bechiri, B. Bouchehit, B. Bou‐Saïd
wiley   +1 more source

First 20 Years of Orbitrap Mass Spectrometry as the Mainstream Analytical Technique

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT This review traces the first 20 years of Orbitrap mass spectrometry as a mainstream high‑resolution and accurate‑mass (HR/AM) technology. It outlines the historical development of the Orbitrap analyzer, the evolution of major instrument families, and the key technological innovations that enabled its widespread adoption. Particular emphasis is
Alexander Makarov
wiley   +1 more source

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