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Time–Temperature Superposition of Polybutadiene Vitrimers [PDF]

open access: goldMacromolecules, 2023
A vitrimer has covalent cross-links that preserve network connectivity but permit topology fluctuations through dynamic exchange reactions. In this work, we investigate the linear rheology of polybutadiene (PB) vitrimers bearing cross-links that exchange via dioxaborolane metathesis.
Ralm G. Ricarte   +4 more
semanticscholar   +6 more sources

TTS package: Computational tools for the application of the Time Temperature Superposition principle [PDF]

open access: yesHeliyon, 2023
The TTS package has been developed in R software to predict the mechanical properties of viscoelastic materials, at short and long observation times/frequencies by applying the Time Temperature Superposition (TTS) principle.
Antonio Meneses   +5 more
doaj   +3 more sources

Optimising dynamic mechanical analysis experiments on soft rubbers for use in time temperature superposition [PDF]

open access: goldMethodsX, 2022
Rubbers are ubiquitous in engineering applications where they are often subjected to loading leading to high strain rate deformation. The strong rate and temperature dependence of rubbers and their composites motivates research into understanding their ...
Akash R. Trivedi   +2 more
doaj   +3 more sources

Fractional Calculus Approach to Reproduce Material Viscoelastic Behavior, including the Time-Temperature Superposition Phenomenon. [PDF]

open access: goldPolymers (Basel), 2022
The design of modern products and processes cannot prescind from the usage of viscoelastic materials that provide extreme design freedoms at relatively low cost.
Genovese A, Farroni F, Sakhnevych A.
europepmc   +4 more sources

The Formation of All-Silk Composites and Time-Temperature Superposition. [PDF]

open access: yesMaterials (Basel), 2023
Extensive studies have been conducted on utilising natural fibres as reinforcement in composite production. All-polymer composites have attracted much attention because of their high strength, enhanced interfacial bonding and recyclability. Silks, as a group of natural animal fibres, possess superior properties, including biocompatibility, tunability ...
King JA, Zhang X, Ries ME.
europepmc   +5 more sources

Time-temperature superposition in viscoelasticity and viscoplasticity for thermoplastics

open access: goldPolymer Testing, 2021
The use of thermoplastics in the automotive industry is continuously increasing. Design of parts require the characterization and numerical modelling of thermo-mechanical behaviour of those materials under wide strain rate (0–300 s−1) and temperature ...
Vincent Dorléans   +4 more
doaj   +3 more sources

Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle. [PDF]

open access: goldPolymers (Basel), 2021
Poly(ethylene 2,5-furandicarboxylate), PEF and poly(ethylene terephthalate), PET, are two polyesters with close chemical structures. It leads to similar thermal, mechanical and barrier properties.
Forestier E   +6 more
europepmc   +4 more sources

The Time–Temperature Superposition of Polymeric Rubber Gels Treated by Means of the Mode-Coupling Theory [PDF]

open access: goldGels
Viscoelastic relaxation measurements on styrene-butadiene rubbers (SBRs) doped with carbon nanotube (CNT) at different concentrations around the sol-gel transition show the time–temperature superposition (TTS).
Domenico Mallamace   +3 more
doaj   +4 more sources

Time-Temperature Superposition Principle in Shearing Tests Compared to Tension Conditions for Polymers Close to Glass Transition. [PDF]

open access: yesInt J Mol Sci, 2023
The well-known principle of time–temperature superposition (TTS) is of prime interest for polymers close to their glass transition. First demonstrated in the range of linear viscoelasticity, it has been more recently extended to large deformations in ...
Billon N   +4 more
europepmc   +2 more sources

Temperature-Time Superposition Effect on Compressive Properties of AZ31B Magnesium Composite Foams [PDF]

open access: goldMetals, 2018
Magnesium composite foams with 10 vol. % of hollow ceramic microspheres (CMs) were prepared by modified melt foaming method. Specimens with homogeneous pore structures were subjected to various heating temperature (150, 250, 320, 400, and 500 °C ...
Xingchuan Xia   +7 more
doaj   +2 more sources

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