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Greenville skarn titanites (2009)

2009
Kennedy, Allen K.   +3 more
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The crystal chemistry of titanite

The chemical substitutions of primary importance in natural titanites are (Al,Fe)3+ + (F,OH)- ⇆ T14+ + O2- , where total Al + Fe is not greater than 30 mol % and Al is usually predominant. Electron microprobe analyses and bond strength considerations suggest that Al prefers the octahedral site in natural titanites, whereas ubiquitous rare earths ...
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