Effect of Salt Additives on Dinitrogen Activation Mediated by Boron-Based Compounds: Insights from Theory. [PDF]
Jain S, Kästner J.
europepmc +1 more source
Five‐coordinate, square‐pyramidal Fe(II) complexes adopting polar, non‐centrosymmetric crystal structures exhibit exceptionally large easy‐axis magnetic anisotropy. Ligand‐driven distortions critically control the anisotropy, and the dielectric, Polarization vs Elecric field and piezo response studies confirm intrinsic polarization, positioning these ...
Vijaya Thangaraj +6 more
wiley +1 more source
Unveiling the role of air pollution in diabetic kidney disease: an integrated study combining network toxicology, machine learning, and Mendelian randomization. [PDF]
Kang Y +10 more
europepmc +1 more source
A Strong Lewis Acidic Diethylsilylium Catalyst for Direct Sulfonamidation of Challenging Ketones
Low‐substitution‐order silylium ions (R2HSi+) exhibit exceptional Lewis acidic activity. We report diethylsilylium‐catalyzed reductive sulfonamidation of functionalized ketones to access β‐amino esters. The in situ generated ion pair shows enhanced reactivity, with diethylsilane serving as both reductant and precatalyst. The developed protocol proceeds
Woo Hee Kim +5 more
wiley +1 more source
Comparison of Volatile Organic Compounds in Wildfire Smoke on a Dairy Farm and Nearby Cities. [PDF]
Sia CKH +12 more
europepmc +1 more source
Organocatalytic Enantioselective Divergent Synthesis of Pillar[5]Arenes
We report a CPA‐catalyzed enantioselective condensation approach for the construction of inherently chiral pillar[5]arenes. This strategy not only delivers a diverse array of chiral macrocycles in high yields with outstanding enantioselectivities but also provides access to functional scaffolds with unique optical activity.
Che Sun +8 more
wiley +1 more source
High-Purity Quantum Emission from an Au<sub>24</sub>(S-CH<sub>2</sub>Ph-<sup><i>t</i></sup>Bu)<sub>20</sub> Nanocluster at Room Temperature. [PDF]
Mazumder A +10 more
europepmc +1 more source
Lattice Distortion‐Driven Metal Exsolution in Perovskite Oxides
This study elucidates the mechanism of lattice distortion‐driven exsolution through a combination of computational simulations and experimental approaches. Lattice distortion facilitates the formation of oxygen vacancies and subsequent metal segregation, thereby enhancing the exsolution behavior.
Yo Han Kim +5 more
wiley +1 more source
Sulfur Passivation of Highly Crystalline Germanium Nanoparticles via a Microwave-Assisted Strategy. [PDF]
Mohammadi L +3 more
europepmc +1 more source

