Gradually bent perylene bisimides (PBIs) isolate structural distortion as the sole variable and exhibit negligible intersystem crossing, uncovering rapid vibrational dephasing as the dominant driver of internal conversion through excited‐state vibrational landscape reorganization.
Wei Zhang +8 more
wiley +1 more source
Elective Robotic Splenectomy for Wandering Spleen-Associated Pancreatitis: A Novel Case Report. [PDF]
Elshabrawi MN +5 more
europepmc +1 more source
Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera +2 more
wiley +1 more source
Intramedullary Nailing for Segmental Tibia Fractures: A Comprehensive Retrospective - Prospective Outcome Analysis in 30 Patients at a Tertiary Care Centre. [PDF]
Thirunthaiyan MR +4 more
europepmc +1 more source
Epimer discrimination remains challenging due to subtle NMR differences. Here, we propose a methodology based on 13C‐RCSA and RDC anisotropic parameters, enabling the assignment of two flexible tetraprenyltoluquinol epimers (1a and 1b) with remote stereoclusters.
Juan Carlos C. Fuentes‐Monteverde +6 more
wiley +1 more source
Simplifying the Diagnosis of Vertical Diplopia: Is It Skew or Not? [PDF]
Igbariye A +6 more
europepmc +1 more source
Light‐Controlled Modulation of 15‐Lipoxygenase‐1 Regulates Intestinal Inflammatory Signaling
The developed target‐guided strategy enables the rational design of diazo‐based photoswitchable inhibitors of 15‐lipoxygenase‐1. Distinct molecular architectures program opposite light‐dependent activity, allowing on‐demand control of enzyme inhibition.
Anastasia Louka +10 more
wiley +1 more source
Floating gallbladder identified on preoperative computed tomography and managed laparoscopically: a case report. [PDF]
Svetlana S, Irina M, Manol S.
europepmc +1 more source
Ein chirales, sattelförmiges Nanographen mit zwei Heptagon‐integrierten [4]Helicenen
Wir präsentieren eine neuartige Synthesestrategie für ein chirales, sattelförmiges Nanographen (cSNG) über eine zweistufige Oxidation eines prochiralen Anthracen‐Vorläufers. Die Scholl‐Oxidation liefert zunächst ein Schlüsselzwischenprodukt mit sp3‐defekten Heptagonen, die anschließende oxidative Dehydrierung ergibt das vollständig konjugierte cSNG ...
Felix Trautner +11 more
wiley +1 more source
The Relationship Between Relative Humeral Retrotorsion Difference and Shoulder Strength Measures in Collegiate Baseball Athletes. [PDF]
Kruseman JK +6 more
europepmc +1 more source

