Results 181 to 190 of about 104,740 (198)

Bending‐Induced Vibrational Landscape Reorganization Governs Energy Dissipation in Perylene Bisimides

open access: yesAngewandte Chemie, EarlyView.
Gradually bent perylene bisimides (PBIs) isolate structural distortion as the sole variable and exhibit negligible intersystem crossing, uncovering rapid vibrational dephasing as the dominant driver of internal conversion through excited‐state vibrational landscape reorganization.
Wei Zhang   +8 more
wiley   +1 more source

Elective Robotic Splenectomy for Wandering Spleen-Associated Pancreatitis: A Novel Case Report. [PDF]

open access: yesClin Case Rep
Elshabrawi MN   +5 more
europepmc   +1 more source

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

open access: yesAngewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera   +2 more
wiley   +1 more source

Anisotropic NMR as a Crucial Tool for Differentiation of Epimers With High Conformational Flexibility

open access: yesAngewandte Chemie, EarlyView.
Epimer discrimination remains challenging due to subtle NMR differences. Here, we propose a methodology based on 13C‐RCSA and RDC anisotropic parameters, enabling the assignment of two flexible tetraprenyltoluquinol epimers (1a and 1b) with remote stereoclusters.
Juan Carlos C. Fuentes‐Monteverde   +6 more
wiley   +1 more source

Simplifying the Diagnosis of Vertical Diplopia: Is It Skew or Not? [PDF]

open access: yesJ Eye Mov Res
Igbariye A   +6 more
europepmc   +1 more source

Light‐Controlled Modulation of 15‐Lipoxygenase‐1 Regulates Intestinal Inflammatory Signaling

open access: yesAngewandte Chemie, EarlyView.
The developed target‐guided strategy enables the rational design of diazo‐based photoswitchable inhibitors of 15‐lipoxygenase‐1. Distinct molecular architectures program opposite light‐dependent activity, allowing on‐demand control of enzyme inhibition.
Anastasia Louka   +10 more
wiley   +1 more source

Ein chirales, sattelförmiges Nanographen mit zwei Heptagon‐integrierten [4]Helicenen

open access: yesAngewandte Chemie, EarlyView.
Wir präsentieren eine neuartige Synthesestrategie für ein chirales, sattelförmiges Nanographen (cSNG) über eine zweistufige Oxidation eines prochiralen Anthracen‐Vorläufers. Die Scholl‐Oxidation liefert zunächst ein Schlüsselzwischenprodukt mit sp3‐defekten Heptagonen, die anschließende oxidative Dehydrierung ergibt das vollständig konjugierte cSNG ...
Felix Trautner   +11 more
wiley   +1 more source

The Relationship Between Relative Humeral Retrotorsion Difference and Shoulder Strength Measures in Collegiate Baseball Athletes. [PDF]

open access: yesOrthop J Sports Med
Kruseman JK   +6 more
europepmc   +1 more source

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