Results 121 to 130 of about 29,050 (250)

Carbon Coking‐Tolerant Perovskite Catalyst Nd0.9Mg0.1Fe0.4Ni0.6O3 for Efficient Methane Dry Reforming

open access: yesCarbon and Hydrogen, EarlyView.
A new perovskite‐type catalyst Nd0.9Mg0.1Fe0.4Ni0.6O3 was developed for methane dry reforming, which exhibited 93.1% CH4 and 94.7% CO2 conversion with 100 h stability run and excellent anti‐coking capability, benefited from in situ exsolved Fe‐Ni alloy nanoparticles. ABSTRACT Perovskite with high temperature stability and tunability is a very promising
Zhenjie Wang, Xingchao Dai, Xinjiang Cui
wiley   +1 more source

Small‐Crystal SAPO‐34 Preparation by Regulating Precursor Mixing Temperature for Methanol‐to‐Olefins Conversion

open access: yesCarbon and Hydrogen, EarlyView.
By tuning the initial mixing temperature from 0°C to 80°C, the crystal size of SAPO‐34 can be adjusted from micro to nanoscale, reflecting a shift from classical single‐crystal growth at low temperatures to non‐classical polycrystalline aggregation at high temperatures.
Guanghua Liang   +4 more
wiley   +1 more source

Interface‐Engineered Li–Ni–O/Ni Heterostructures With Tunable Vacancies on Biochar Enable Biomass‐to‐Hydrogen Conversion

open access: yesCarbon Energy, EarlyView.
This study shows that lithium induces Li–Ni–O/Ni heterostructures on biochar, creating oxygen vacancies and optimal acid–base environments that enhance steam activation and suppress carbon deposition. These interfacial effects and synergistic modulation lead to high hydrogen yields at moderate temperatures, providing a scalable catalyst design strategy
Jiali Guo   +7 more
wiley   +1 more source

Beyond Furnaces: Harnessing In Situ Joule Heating for Efficient C1 Catalysis

open access: yesCarbon Energy, EarlyView.
Joule‐heated catalysis directly converts electrical energy into localized heat within conductive catalysts, overcoming the heat‐transfer limitations of conventional furnaces. This review summarizes recent advances in C1 molecule conversion, including CO2 methanation, reforming for hydrogen production, and HCHO/CO oxidation, while highlighting ...
Xue Kong   +8 more
wiley   +1 more source

Unveiling the Potential of Metal and Non‐Metal Modified Porous Carbon for the Electrochemical Reduction of CO2

open access: yesCarbon Energy, EarlyView.
Earth‐abundant metal‐ and non‐metal‐modified porous carbons offer a highly tunable platform for electrochemical CO2 reduction. This review shows how electronic interactions, active‐site coordination, pore architecture, and cooperative catalytic effects jointly govern intermediate stabilization, product selectivity, and device‐relevant CO2RR performance.
Hussein A. Younus   +4 more
wiley   +1 more source

Mechanistic Insights Into Sustainable Catalytic Pyrolysis of Biomass‐Derived Ferulic Acid: The Role of Alumina Regeneration

open access: yesChemistry – A European Journal, EarlyView.
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik   +11 more
wiley   +1 more source

Using Displacement‐Assisted Desorption to Identify Reactive Intermediates: Ring‐Fused Porphyrins on Cu(111)

open access: yesChemistry – A European Journal, EarlyView.
We propose a novel displacement‐assisted approach for temperature‐programmed desorption (TPD), allowing for the detection of reactive intermediates of on‐surface reactions. We demonstrate the approach by investigating the temperature‐dependent ring fusion reactions (cyclodehydrogenations) of tetraphenylporphyrin on Cu(111), revealing the quantitative ...
Simon Steinbach   +4 more
wiley   +1 more source

TPD, CS, & Complex Systems

open access: yes
Ph.D research for peer reviewed journal submissions on TPD as primary theoretical framework adapted for CS and Complex Adaptive Systems ...
Jonathon T Huckvale
core   +1 more source

Impact of Trace Water on the Macroscopic Activity of Commercial Ammonia Cracking Catalysts Under Process‐Relevant Conditions

open access: yesChemie Ingenieur Technik, EarlyView.
This study evaluates how small water impurities—typical in ammonia cracking feedstock—affect catalyst performance at elevated pressures and temperatures. By decoupling permanent degradation from reversible inhibition, the findings highlight trace water as a significant factor for reliable catalyst screening and industrial ammonia cracking scale‐up ...
Bruno V. P. Lago   +6 more
wiley   +1 more source

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