Results 121 to 130 of about 42,970 (286)

Polycarbonate Vitrimers and Dynamic Co‐Networks From Epoxide/Carbon Dioxide Copolymerization

open access: yesMacromolecular Rapid Communications, EarlyView.
This work demonstrates how CO2‐derived poly(propylene carbonate) and poly(cyclohexene carbonate) backbones influence vitrimer thermo‐mechanical behavior. By tuning backbone composition, epoxide crosslinker chemistry and blend ratios, the crosslinked materials span a wide property window, from highly extensible to stiff, glassy networks, establishing an
Satej S. Joshi   +3 more
wiley   +1 more source

Chemically and Mechanically Recyclable Polyolefins Incorporating Covalent Adaptable Networks

open access: yesMacromolecular Rapid Communications, EarlyView.
Low‐molecular‐weight polypropylene is converted into a crosslinked polyolefin containing a covalently adaptable network. The semicrystalline material remains melt‐processable and mechanically recyclable. Its thermal and mechanical properties are comparable to commercial polyolefins.
Andrii Tiiara   +4 more
wiley   +1 more source

Design of biodiesel production processes by base-catalyzed transesterification

open access: yes, 2012
A lot of efforts have been carried out to develop an alternative fuel for the current energy and environment questions. Biodiesel which is synthesized by transesterification of plant oils and animal fat is a real alternative fuel for its renewable and ...
Shi HY(史洪岩)   +2 more
core  

Modelagem e simulação de um reator tubular contínuo para a produção de biodiesel [PDF]

open access: yes, 2012
Tese (doutorado) - Universidade Federal de Santa Catarina, Centro Tecnológico. Programa de Pós-Graduação em Engenharia QuímicaO impacto ambiental devido ao uso de combustíveis fósseis e as questões políticas envolvendo seu uso tem impulsionado a busca ...
Galante, Raquel Manozzo
core  

Efficient and chemoselective alkyl bromoacetate-Zn mediated transesterification method

open access: yes, 2003
Alkyl bromoacetates were shown to be versatile transesterification reagents. Isoxazoles underwent chemoselective transesterification when treated with alkyl bromoacetate-Zn in THF at reflux.
Er, Mustafa, COSKUN, N
core   +1 more source

Thiolate Salt Mediated Dynamic Silyl Ether Exchanges for Polymer Network Design and Deconstruction

open access: yesMacromolecular Rapid Communications, EarlyView.
This work introduces thiolate salts as mediators for dynamic silyl ether exchange. This platform enables the synthesis of reprocessable covalent adaptable polymer networks (CANs) and allows for sterically controlled, and tunable deconstruction of silyl ether‐containing thermosets.
Pierce T. Bombard   +9 more
wiley   +1 more source

Analysis of Carbohydrates and Glycoconjugates by Matrix‐Assisted Laser Desorption/Ionization Mass Spectrometry: An Update for 2023–2024

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT The use of MALDI mass spectrometry for the analysis of carbohydrates and glycoconjugates is a well‐established technique and this comprehensive review is the twelfth update of the original article published in 1999 and brings coverage of the literature to the end of 2024.
David J. Harvey
wiley   +1 more source

Robust β‐myrcene block copolymer elastomeric vitrimers

open access: yesPolymer International, EarlyView.
Myrcene‐based vitrimeric elastomers were compared: statistical (poly(styrene‐stat‐myrcene‐stat‐AAEMA)] versus ‘hard–soft’ diblock (poly(styrene)‐block‐poly(myrcene‐co‐AAEMA)). The diblock's ability to anchor the glassy poly(styrene) blocks in a self‐assembled microstructure was effective – leading to four times higher tensile stress and ten times ...
Chong Yang Du   +2 more
wiley   +1 more source

Unsaturated biobased polyesters from bicyclic α‐pinene‐based diols

open access: yesPolymer International, EarlyView.
We present the synthesis of four biosourced unsaturated polyesters made from chiral terpene‐based diols and esters of renewable diacids. The resulting materials harbor a bicyclic pinene ring in their backbones which leads to enhanced thermal properties while still conferring susceptibility to enzyme hydrolysis for chains having a cis alkene.
Ganapathy Ranjani   +4 more
wiley   +1 more source

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