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Intramolecular Transesterification of Pivaloylated monosaccharides
2001Intramolecular migrations of acyls are well known in carbohydrate chemistry. These transesterifications are most often acid or base catalysed, and the mechanism of such reactions has been described (1). Especially prone to migrations are acetyls which spontaneuosly migrate along the sugar ring even under neutral conditions, in organic solvents (2 ...
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