Results 71 to 80 of about 17,691 (234)

Biobased Epoxidized Castor Oil Covalent Adaptable Networks Adhesives Reinforced with Recycled Carbon Fibers

Macromolecular Rapid Communications, EarlyView.
It is reported the design of biobased sustainable, smart, and functional adhesives achieved dispersing recycled carbon fibers into biobased epoxy monomer. ABSTRACT The development of sustainable, smart, and functional adhesives is crucial in advancing environmentally friendly materials.
Alberto Cellai, Rafael Turra Alarcon, Bernhard Sölle, Elisabeth Rossegger, Valentina Casalegno, Milena Salvo, Marco Sangermano   +6 more
wiley   +1 more source

Polycarbonate Vitrimers and Dynamic Co‐Networks From Epoxide/Carbon Dioxide Copolymerization

Macromolecular Rapid Communications, EarlyView.
This work demonstrates how CO2‐derived poly(propylene carbonate) and poly(cyclohexene carbonate) backbones influence vitrimer thermo‐mechanical behavior. By tuning backbone composition, epoxide crosslinker chemistry and blend ratios, the crosslinked materials span a wide property window, from highly extensible to stiff, glassy networks, establishing an
Satej S. Joshi, Sophia Aracri, Mark D. Foster, James M. Eagan   +3 more
wiley   +1 more source

transesterification

Citation: 'transesterification' in the IUPAC Compendium of Chemical Terminology, 5th ed.; International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.15425 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Temperature‐Driven Switching Between Block, Near‐Statistical, and Gradient Copolymers Enabled by Multinuclear Aluminum Catalysis

Macromolecular Rapid Communications, EarlyView.
A single multinuclear aluminum catalyst enables temperature‐driven switching between block‐enriched, near‐statistical, and gradient CL/LA copolymer microstructures. Modulation of propagation and exchange processes within one catalytic platform provides a unified kinetic–thermodynamic framework for sequence control in biodegradable polyester ...
Yoseph Kim, So Han Kim, Gue Seon Lee, Jeung Gon Kim, Youngjo Kim   +4 more
wiley   +1 more source

Chemically and Mechanically Recyclable Polyolefins Incorporating Covalent Adaptable Networks

Macromolecular Rapid Communications, EarlyView.
Low‐molecular‐weight polypropylene is converted into a crosslinked polyolefin containing a covalently adaptable network. The semicrystalline material remains melt‐processable and mechanically recyclable. Its thermal and mechanical properties are comparable to commercial polyolefins.
Andrii Tiiara, Bernadine Daichendt, Sergiy Minko, Olga Kuksenok, Igor Luzinov   +4 more
wiley   +1 more source

Reprocessable Disulfide‐Based Vitrimers with Adhesive Properties

Macromolecular Rapid Communications, EarlyView.
A dual‐curing strategy combining UV‐induced thiol–ene polymerization and thermal thiol–epoxy curing was used to prepare disulfide‐based vitrimer networks with reprocessable, recyclable, and adhesive properties enabled by dynamic disulfide exchange. ABSTRACT A family of disulfide (S–S) containing thiol–vinyl–epoxy dynamic networks are presented.
Sasan Moradi, Osman Konuray, Javier G. Valverde‐Bastidas, Xavier Fernández‐Francos, Xavier Ramis   +4 more
wiley   +1 more source

Reprocessable Vitrimers From Post‐Consumer Polyolefin Blends: Elucidating Phase‐Selective Dynamic Networks

Macromolecular Rapid Communications, EarlyView.
Reactive melt extrusion utilizing nitroxide‐mediated silyl ether chemistry transforms post‐consumer high‐density polyethylene and polypropylene blends into robust vitrimers. Featuring highly phase‐selective crosslinking, these upcycled materials combine thermoset‐like dimensional stability at elevated temperatures with dynamic melt‐reprocessability ...
Subhaprad Ash, Rishi Sharma, Li Xie, Muhammad Rabnawaz   +3 more
wiley   +1 more source

Second‐Life Thermoset Manufacturing via Mild Solvolysis of Epoxy‐Matrix Composites and Wet‐Laid Mat Production

Polymer Composites, EarlyView.
From end‐of‐life pultruded CFRP profiles (1) to second life composites (7) through mild solvolysis (2,3), wet‐laid nonwoven mat fabrication (4), resin impregnation (5), and compression molding (6). ABSTRACT The growing use of carbon fiber–reinforced thermosets has led to the accumulation of significant composite waste, posing environmental and economic
Ehsan Zolfaghari, Fabian Rechsteiner, Violetta Schumm, Emanuela Muscolino, Sabina Alessi, Nadka Tz. Dintcheva, Clelia Dispenza   +6 more
wiley   +1 more source

Insights into kinetics and reaction mechanism of acid-catalyzed transesterification synthesis of diethyl oxalate

Resources Chemicals and Materials
The catalytic performance of different acidic catalysts for diethyl oxalate synthesis from the one-step transesterification of dimethyl oxalate and ethanol was evaluated.
Naiwen Zhang, Rui Xia, Siyu Wan, Xinyang Xiong, Jinggang Zhao, Jun Zhou, Lei Shi   +6 more
doaj   +1 more source

Enhancing PET Printability via Solid‐State Polymerization: Structure‐Processing‐Properties Relationships

Polymer Engineering &Science, EarlyView.
Solid‐state polymerization (SSP) enhances rheological properties, filament stability, and adjusts crystallization issues for improved PET 3D printability. ABSTRACT This paper aims to investigate the impact of solid‐state polymerization (SSP) on the printability of PET for 3D printing.
Benjamin Sandei, Noah Nohadani, Cécile Nouvel, Valérie Massardier‐Nageotte, Claire Barrès, Mohamed Yousfi   +5 more
wiley   +1 more source