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The structures of transition metal-transition metal alloys
Journal of Solid State Chemistry, 1984Abstract A structure map using the average electron count and d orbital energy difference as indices is used to sort transition metal alloys of stoichiometry AB . The gross features of the map are mimicked by tight-binding calculations. The inclusion of s orbitals on the metal atoms appear to be important in the determination of alloy structure ...
Jeremy K. Burdett, Timothy J. McLarnan
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Heavy fermions in transition metals and transition-metal oxides [PDF]
The European Physical Journal B - Condensed Matter, 2003 Heavy-fermion formation in transition metals and transition-metal oxides is reviewed and compared to observations in canonical f-derived heavy-fermion systems. The work focuses on the dynamic susceptibilities which reveal a characteristic temperature and frequency dependence and which can be unambiguously determined via nuclear magnetic resonance and ...
Krug von Nidda, Hans-Albrecht +4 more
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Critical size for a metal-nonmetal transition in transition-metal clusters
Physical Review B, 1994Based on a tight-binding Friedel model for the density of d-electron states, we investigate the critical size for the metal-nonmetal transition in transition-metal clusters. An analytic equation for the critical size has been introduced for the cluster with close-packed structure. At the critical point (about 30--50 atoms), the density of states of the
, Zhao, , Chen, , Wang
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Photocurrent Generation with Transition Metal Nitrides and Transition Metal Carbides
2018 20th International Conference on Transparent Optical Networks (ICTON), 2018Photoexcited hot carriers in metals can be injected into adjacent semiconductors to collect sub-bandgap photons. In the current work, we experimentally demonstrate that transition metal nitrides and transition metal carbides can act as metals and generate hot electrons by optical illumination similar to metals.
Satoshi Ishii +2 more
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Density functional theory for transition metals and transition metal chemistry
Physical Chemistry Chemical Physics, 2009We introduce density functional theory and review recent progress in its application to transition metal chemistry. Topics covered include local, meta, hybrid, hybrid meta, and range-separated functionals, band theory, software, validation tests, and applications to spin states, magnetic exchange coupling, spectra, structure, reactivity, and catalysis,
Christopher J, Cramer, Donald G, Truhlar
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ChemInform, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Donald J. Darensbourg, Cesar G. Ortiz
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AbstractFor Abstract see ChemInform Abstract in Full Text.
Donald J. Darensbourg, Cesar G. Ortiz
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Adsorption of Transition Metal Atoms on a Transition Metal Substrate
Journal of Vacuum Science and Technology, 1972The binding energy of transition atoms adsorbed on a transition metal of the same series is studied in a tight binding model using a moment’s expansion technique. The general trends of the variation of the binding energy with the number of adatom d electrons are similar for all the substrates.
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2013
This chapter assesses the d-block elements, which form Groups 3–11 and are collectively often referred to as the transition metals. The common feature of these elements is the presence of a partially filled d sub-shell. It is the presence of this partly filled shell which is responsible for most of the special properties which set the transition metals
James Keeler, Peter Wothers
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This chapter assesses the d-block elements, which form Groups 3–11 and are collectively often referred to as the transition metals. The common feature of these elements is the presence of a partially filled d sub-shell. It is the presence of this partly filled shell which is responsible for most of the special properties which set the transition metals
James Keeler, Peter Wothers
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Transition metal nitroprussides: Crystal and electronic structure, and related properties
Coordination Chemistry Reviews, 2021Yosuan Avila Garcia +2 more
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