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Cathodic reduction of layered transition metal chalcogenides
Materials Research Bulletin, 1974Abstract Layered binary transition metal chalcogenides MX 2 (M = transition metal, X=S, Se) may be reduced electrochemically in aqueous electrolyte solutions to give hydrated polyelectrolyte compounds (A x ) x+ (H 2 O) y [MX 2 ] x− (I). The latter consist of negatively charged layers [MX 2 ] x− with hydrated cations A + positioned between the ...
R. Schöllhorn, H. Meyer
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Transition Metal Chalcogenides for Oxygen Reduction
2013Transition metal chalcogenide materials represent nowadays a new family of alternative materials for the cathode oxygen reduction reaction (ORR). During the last decade, the efforts have been concentrated in developing this kind of materials due to their capacity to remain selective and tolerant in the presence of small organics in acid as well as in ...
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Stanene, Mxene and Transition Metal Chalcogenides
In recent years, there has been a notable surge of interest in Stanene, MXene, and Transition Metal Chalcogenides. The chapter offers a comprehensive exploration of these cutting-edge 2D materials and their multifaceted applications. Stanene, with its remarkable quantum effects and physicochemical properties, holds promise for the future of ...Rakshit Pathak +3 more
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Crystallographic Studies of Intercalated Transition Metal Chalcogenides
2023Crystallography, in simplest terms, is the study of crystals, their atomic arrangement,symmetry, and morphology. This knowledge is applied across disciplines ranging from determining the structure of geological minerals to biologically important compounds such as deoxyribonucleic acid(DNA) to high-temperature superconductors and quasi-crystals.
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Rare-Earth Transition-Metal Chalcogenides
Chemical Reviews, 2002Kwasi, Mitchell, James A, Ibers
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ASYMMETRIC INTERCALATION OF TRANSITION METAL CHALCOGENIDES
Layered transition metal chalcogenides (TMCs) offer a versatile platform for novel quantum properties through intercalation chemistry. By intercalating molecular species into the van der Waals gaps, one can modulate the host structure, tune electronic correlations, and even break the symmetries of the structure.openaire +1 more source
Non-Quenchability of Some Transition-Metal Chalcogenides
1977The establishment of the phase diagrams of transition-metal chalcogenides has so far been based mostly on the quenched specimens. Some of them, however, are not quenchable at all. The present report will briefly summarize the behaviors of those compounds through the comparison between the various measurements of quenched specimens and the in-situ ...
M. Nakahira +3 more
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1979
The occurrence of alkali metal intercalated compounds from layered chalcogenides with two dimensional structures was reported for the first time in 1965 by Rudorff [1]. Rapidly this field of research proved very fruitful. A first exhaustive study in the more general framework of ternary chalcogenides with alkali and transition metals has been given in ...
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The occurrence of alkali metal intercalated compounds from layered chalcogenides with two dimensional structures was reported for the first time in 1965 by Rudorff [1]. Rapidly this field of research proved very fruitful. A first exhaustive study in the more general framework of ternary chalcogenides with alkali and transition metals has been given in ...
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Intercalation Chemistry of Tetrahedral Transition Metal Chalcogenides
2018Tetrahedral transition metal chalcogenides (TTMCs), which have a common layered structural motif that could carry novel functionalities on account of the $d$-orbital filling. These metal chalcogenide layers can be held together either by pure van der Waals forces, ionic forces, or even hydrogen bonding, depending on the guest species intercalated in ...
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