Enantiomerically Pure <i>ansa</i>-<i>η</i><sup>5</sup>-Complexes of Transition Metals as an Effective Tool for Chirality Transfer. [PDF]
Kovyazin PV, Khalilov LM, Parfenova LV.
europepmc +1 more source
The dielectric properties of clays are studied on the level of individual monolayers and functional double stacks. The material breakdown characteristics and charge storage performance are analyzed. For illustration, a defined charge pattern representing a cuneiform character is produced, written into a microscopic clay tile, referencing the origins of
Sebastian Gödrich +6 more
wiley +1 more source
Modulating Electrochemical CO2 Reduction Pathways via Interfacial Electric Field
Engineering interfacial electric fields in Cu/ITO electrodes enables precise control of CO2 reduction pathways. Charge transfer from Cu to ITO generates positively charged Cu species that steer selectivity from ethylene toward methane. This work demonstrates how interfacial electric‐field modulation can direct reaction intermediates and transform ...
Mahdi Salehi +7 more
wiley +1 more source
Electronic and magnetic properties of the HfO2 monolayer engineered by doping with transition metals and nonmetal atoms towards spintronic applications. [PDF]
Han NT, Guerrero-Sanchez J, Hoat DM.
europepmc +1 more source
The first cryo‐EM visualization and quantification of oriented Photosystem I (PSI) on single‐layer graphene is reported. Domain‐specific covalent anchoring of PSI, with the reducing side of the biophotocatalyst toward graphene, promotes three‐fold higher anodic photocurrent generation compared to a randomly physisorbed counterpart. This approach allows
Miriam Izzo +6 more
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Tailoring Superatomic Stability with Transition Metals in Silicon Cages: Shrinking to M@Si15 (M = Re, Os, Ir). [PDF]
Ichikawa T +3 more
europepmc +1 more source
Positive‐Tone Nanolithography of Antimony Trisulfide with Femtosecond Laser Wet‐Etching
A butyldithiocarbamic acid (BDCA) etchant is used to fabricate various micro‐ and nanoscale structures on amorphous antimony trisulfide (a‐Sb2S3) thin film via femtosecond laser etching. Numerical analysis and experimental results elucidate the patterning mechanism on gold (reflective) and quartz (transmissive) substrates.
Abhrodeep Dey +12 more
wiley +1 more source
Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications. [PDF]
Sun S, Choe J, Cho J.
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Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76)
Luminescent MOF‐76 materials based on Eu(III) and mixed Eu(III)/Y(III) show rapid and reversible changes in emission intensity in response to O2 with very short response times. The effect is based on triplet quenching of the linker ligands that act as photosensitizers. Average emission lifetimes of a few milliseconds turn out to be mostly unaffected by
Zhenyu Zhao +5 more
wiley +1 more source

