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Structural Exploration of Zirconium Metal–Organic Frameworks Through Linker Desymmetrization and Modulator Compensation

open access: yesAdvanced Materials, EarlyView.
A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang   +8 more
wiley   +1 more source

COFs on MOFs: Layer‐by‐Layer Synthesis of MOF@COF Nanoparticles with Synergistic Adsorption

open access: yesAdvanced Materials, EarlyView.
A layer‐by‐layer strategy enables the growth of crystalline covalent organic framework (COF) shells on metal–organic framework nanoparticles, creating core–shell structures with tunable porosity. Ordered interstitial mesopores are formed during shell growth, which are connected with the COF's intrinsic micropores, thereby enhancing water sorption. This
Ana Guillem‐Navajas   +11 more
wiley   +1 more source

Porous Iridium Oxide Inverse Opal Catalysts Enable Efficient PEM Water Electrolysis

open access: yesAdvanced Materials, EarlyView.
Porous iridium‐based inverse opal (IrOx‐IO) structures are introduced as high‐performance, unsupported PEM‐WE anode catalysts. Their electrochemical behavior is analyzed through porosity/surface area tuning, voltage breakdown, and circuit modeling.
Sebastian Möhle   +4 more
wiley   +1 more source

Silver Ions as Ambipolar Dopants in InAs Nanocrystal Solids

open access: yesAdvanced Materials, EarlyView.
Ag⁺ ions post‐introduced into InAs nanocrystal films act as ambipolar dopants whose effect depends on host polarity and dopant concentration. In n‐type InAs nanocrystal films, Ag⁺ occupies interstitial sites to yield n‐type doping effect, whereas in Zn‐doped p‐type InAs nanocrystal films, it first forms p‐type surface doping effect and later induces n ...
Hwichan Cho   +11 more
wiley   +1 more source

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