Über Derivate des Hydrazins, VIII [1] Bis(trimethylsilyl)amino-isocyanat und -isothiocyanat / On Derivatives of Hydrazine, VIII [1] Bis(trimethylsilyl)amino-isocyanate and -isothiocyanate [PDF]
Zeitschrift für Naturforschung B, 1978 Abstract Bis(trimethylsilyl)aminoisocyanate (1) is formed by reaction of the hydrazides LiN2(SiMe3)3 or Li2N2(SiMe3)2 with phosgene. Bis(trimethylsilyl)aminoisothiocyanate (2) is obtained by thermolysis of the hydrazide (Me3Si)3N2CSSLi, which is readily prepared from LiN2(SiMe3)3 and carbon disulfide.
Nils Wiberg, Gerhard Hübler
openaire +3 more sources
PECULIARITIES OF ISOCYANATES INTERACTION WITH HYDRAZINE DERIVATIVES
Тонкие химические технологии, 2018 The results of studies on chemical transformations of organic and organosilicon isocyanates in their interaction with hydrazine derivatives have been summarized in this review.
A. D. Kirilin +4 more
doaj +1 more source
Kinetic and chemorheological modeling of thermosetting polyurethanes obtained from an epoxidized soybean oil polyol crosslinked with glycerin [PDF]
arXiv, 2022 Thermosetting polyurethanes were obtained using an aromatic isocyanate and a hydrophobic polyol formulation obtained from epoxidized soybean oil (ESO) crosslinked with glycerin. A systematic DSC analysis of the effect of catalyst type, crosslinker concentration, isocyanate index and ESO crystallization on the cure kinetics was conducted.
arxiv
Exploring the transport properties of equatorially low coordinated erbium single ion magnets [PDF]
, 2019 Single-molecule spin transport represents the lower limit of miniaturization of spintronic devices. These experiments, although extremely challenging, are key to understand the magneto-electronic properties of a molecule in a junction. In this context, theoretical screening of new magnetic molecules provides invaluable knowledge before carrying out ...
arxiv +1 more source
Identification of Methyl Isocyanate and Other Complex Organic Molecules in a Hot Molecular Core, G31.41+0.31 [PDF]
, 2020 G31.41+0.31 is a well known chemically rich hot molecular core (HMC). Using Band 3 observations of Atacama Large Millimeter Array (ALMA), we have analyzed the chemical and physical properties of the source. We have identified methyl isocyanate (CH3NCO), a precursor of prebiotic molecules, towards the source.
arxiv +1 more source
Chemistry – A European Journal, Accepted Article.Structurally‐modified aminoglycosides, such as kanamycin, have shown promise as antibiotics and premature termination codon read‐through drugs to fight against drug‐resistant bacteria and to treat genetic diseases, respectively. Therefore, research on developing and discovering aminoglycoside antibiotics has recently increased.
Kanae Hosomi +7 more
wiley +1 more source
Solvation chemistry in liquid electrolytes for rechargeable lithium batteries at low temperatures
EcoEnergy, EarlyView.This review discusses the solvation chemistry of the electrolyte in lithium batteries (LBs) at low temperature (LT). It highlights the Li+ solvation chemistry in LBs at LT, including the properties of the solvent, the solvation structure of Li+, strategies of tuning solvation chemistry via solvents/lithium salts, and characterization techniques of ...
Houzhen Li, Chuncheng Yan, Shuhua Wang
wiley +1 more source
Reactivity of an ortho‐Phenylene‐bridged Al/P Frustrated Lewis Pair Towards Small Molecules
European Journal of Inorganic Chemistry, Accepted Article.Frustrated Lewis Pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. In this paper, we present the first ortho‐phenylene bridged Al/P‐based FLP with only one phosphine moiety. The title compound was employed in various reactions with small molecules featuring different functional ...
Melina E. A. Dilanas, Frank Breher
wiley +1 more source
Re-exploring Molecular Complexity with ALMA (ReMoCA): Interstellar detection of urea [PDF]
A&A 628, A10 (2019), 2019 Urea, NH2C(O)NH2, is a molecule of great importance in organic chemistry and biology. Two searches for urea in the interstellar medium were reported in the past, but neither were conclusive. We want to take advantage of the increased sensitivity and angular resolution provided by ALMA to search for urea toward the hot cores embedded in the high-mass ...
arxiv +1 more source
Synthesis of Oligo‐ and Polyethylene‐Polyamide‐6 Diblock Polymers
Journal of Polymer Science, EarlyView.ABSTRACT A route for the development of a potential filament material for FFF 3D printing based on HDPE‐PA‐6 diblock copolymers is described. The approach consists of inducing an anionic caprolactam polymerization using a hydroxy‐functionalized polyethylene macroinitiator.
Elsa M. Schoeneberger +1 more
wiley +1 more source