Results 51 to 60 of about 165 (92)

ChemInform Abstract: Xenon Difluoride—Trimethylsilyl Isocyanate—Triflic Acid as a New System for the Amination of Aromatic Compounds.

ChemInform, 2001
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Peter J. Stang, Namig Sh. Pirkuliev, Namig Sh. Pirkuliev, Valery K. Brel, Novruz G. Akhmedov, Nikolai S. Zefirov, Nikolai S. Zefirov   +6 more
  +6 more sources

ChemInform Abstract: Interaction of Trimethylsilyl Isocyanate with Xenon Difluoride and Fluoroxenonium Triflate in the Presence of Alkenes.

ChemInform, 2001
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Valery K. Brel, Nikolai S. Zefirova, Peter J. Stang, N. G. Akhmedov, Namig Sh. Pirkuliev, Namig Sh. Pirkuliev   +5 more
  +6 more sources

Sodium Bis(trimethylsilyl)amide in the “One‐Flask” Transformation of Isocyanates to Cyanamides.

ChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Chun-Yen Chen, Mou Yung Yeh, Fung Fuh Wong   +2 more
  +6 more sources

ChemInform Abstract: “One‐Flask” Transformation of Isocyanates and Isothiocyanates to Guanidine Hydrochlorides by Using Sodium Bis(trimethylsilyl)amide.

ChemInform, 2010
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Mou-Yung Yeh, Chun Yen Chen, Yu-Ying Huang, Fung Fuh Wong, Hui-Chang Lin, Kun-Lung Chen, Jiann-Jyh Huang   +6 more
  +6 more sources

ChemInform Abstract: REACTION OF DITHIOPHOSPHORIC ACIDS WITH TRIMETHYLSILYL ISOCYANATE AND ISOTHIOCYANATE

Chemischer Informationsdienst, 1979
AbstractDas O,O‐Dimethyl‐dithiophosphat (Ia) reagiert mit dem Isothiocyanat (II) zu einem Gemisch der kristallinen Verbindung (V) und dem flüssigen Silylester (III).
R. T. Nigametzyanov, R. A. Cherkasov, A. N. Pudovik, G. A. Kutyrev   +3 more
openaire   +3 more sources

Reactions of Group IV organometallic compounds. Part XXVI. Insertion reactions of isocyanates and isothiocyanates to N-trimethylsilyl-(diphenylmethylene)amine and subsequent [4 + 2] cycloadditions of isocyanates with their adducts

Journal of the Chemical Society, Perkin Transactions 1, 1972
N-Trimethylsilyl(diphenylmethylene)amine reacted with 1 mol. equiv. of methyl, phenyl, or benzoyl isocyanate, and with the corresponding isothiocyanates, by the selective cleavage of the Si–N bond. The n.m.r. spectra of the 1:1 insertion product (III)–(VIII) showed the non-equivalency of trimethylsilyl proton signals at low temperature.
Isamu Matsuda, Yoshio Ishii, Kenji Itoh
openaire   +3 more sources

Formation of copper(I) isocyanate complexes by the reaction of carbon dioxide and copper(I) bis(trimethylsilyl)amide complexes

Journal of the Chemical Society, Chemical Communications, 1977
Copper(I) bis(trimethylsilyl)amide deoxygenates carbon dioxide in the presence of an added ligand to produce hexamethyldisiloxane and a copper(I) isocyanate complex which is converted into an alkyl isocyanate by treatment with an alkyl iodide.
Tetsuo Tsuda, Hiroshi Washita, Takeo Saegusa   +2 more
openaire   +3 more sources

Curtius Degradation Utilizing Trimethylsilyl Azide. A facile isocyanate synthesis

Synthetic Communications, 1972
Abstract We wish to report a modification of the Curtius Degradation which facilely affords high yields of isocyanates from acid chlorides or anhydrides under “single-pot” conditions. Trimethylsilyl acide attacks the reactive carbonyl groups of cyclic anhydrides and isomaleimides according to Eqn. 1, giving formally a Curtius Degradation product.
William R. Peterson, Stephen S. Washbume
openaire   +3 more sources

ChemInform Abstract: KINETICS AND MECHANISM OF THE REACTION OF S‐(TRIMETHYLSILYL) ESTERS OF PHOSPHORUS DITHIO ACIDS WITH ALKYL ISOCYANATES.

Chemischer Informationsdienst, 1985
AbstractDie Dithiophosphate (I) reagieren mit Alkylisocyanaten wie z.B. (II) unter intramolekularer S‐N‐Wanderung über (III) zu den N‐Thiophosphoryl‐thiocarbamaten (IV).
A. V. Lygin, G. A. Kutyrev, A. N. Pudovik, R. A. Cherkasov   +3 more
openaire   +3 more sources

Reaction of trimethylsilyl cyanide with isocyanates and carbodiimides

Journal of Organometallic Chemistry, 1979
Abstract Trimethylsilyl cyanide reacts with isocyanates to give 1 2 cycloadducts, 5-(trimethylsilylimino)imidazolidine-2,4-diones, in high yield. The reaction of trimethylsilyl cyanide with carbodiimides proceeded in the presence of a catalytic amount of aluminum trichloride to afford 1 1 adducts, N-trimethylsilyl-1-cyanoformamides.
Iwao Ojima, Shin-ichi Inaba
openaire   +3 more sources