Results 101 to 110 of about 295 (151)

Reactions of 1-substituted 2,4,6-trinitrobenzenes with nucleophiles

open access: yesCollection of Czechoslovak Chemical Communications, 1979
Rate constants have been determined of nucleophilic aromatic substitution of 2,4,6-trinitrophenyl methyl ether (Ia), 2,4,6-trinitrophenyl ethanoate (Ic), 2,4,6-trinitrochlorobenzene (Ib), 2,4,6-trinitrodiphenyl ether (Id), 2,4,6-trinitro-4'-bromodiphenyl
Jaromir Kaválek   +2 more
exaly   +2 more sources
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C–HLO Hydrogen bonded multi-point recognition in molecular assemblies of dibenzylidene ketones and 1,3,5-trinitrobenzenes

open access: yesJournal of Materials Chemistry, 1997
Dibenzylideneacetone1a, 2,5-dibenzylidenecyclopentanone 1b, 2,6-dibenzylidenecyclohexanone 1c and 2,5-dibenzylidenecyclopent-3-enone 1d form crystalline stoichiometric complexes with 1,3,5-trinitrobenzene 2a, picryl chloride 2b and picric acid 2c.
Kumar Biradha   +2 more
exaly   +2 more sources

ASSESSMENT OF ENVIRONMENTAL HAZARDS OF 1,3,5-TRINITROBENZENE

Journal of Toxicology and Environmental Health, 1997
The remedial investigation/feasibility studies conducted at certain Army installations showed a need to clean up contaminated sites, where high levels of ammunition chemicals such as 2,4,6-trinitrotoluene (TNT), 1,3,5-trinitrobenzene (TNB), 1,3-dinitrobenzene (DNB), and their degradation products/metabolites were detected in surface soil and ...
G, Reddy   +4 more
openaire   +3 more sources

First-principles study of crystalline mono-amino-2,4,6-trinitrobenzene, 1,3-diamino-2,4,6-trinitrobenzene, and 1,3,5-triamino-2,4,6-trinitrobenzene

Journal of Molecular Structure: THEOCHEM, 2009
Abstract The electronic structure and thermodynamic properties of crystalline mono-amino-2,4,6-trinitrobenzene (MATB), 1,3-diamino-2,4,6-trinitrobenzene (DATB), and 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) have been comparatively studied using density functional theory in the local density approximation.
Weihua Zhu   +3 more
openaire   +1 more source

Reaction of ammonia with trinitrobenzene sulfonic acid

Analytical Biochemistry, 1980
Abstract 2,4,6-Trinitrobenzene sulfonic acid reacts stoichiometrically with ammonia in tetraborate buffer within 20 min at 35°C to give a compound (presumably picramide) with an absorbance macimum at 420 nm and ϵm 2.02 ± 0.07 × 104 m −1 cm−1 in the presence of 1.0 m m sulfite ions.
J R, Whitaker, P E, Granum, G, Aasen
openaire   +2 more sources

Crystal growth of trinitrobenzene and trinitrotoluene

Materials Research Bulletin, 1973
Abstract Single crystals of 1,3,5-trinitrobenzene (TNB) and 2,4,6-trinitrotoluene (TNT) up to two centimeters in size were grown by the precipitant infusion method. Examination by an X-ray imaging method showed that the crystals, or substantial portions of them, are sufficiently perfect for many investigations.
W. Fisco, O. Haase
openaire   +1 more source

Trifluoromethylation of 1,3,5-trinitrobenzene

Journal of Fluorine Chemistry, 1989
Abstract The trifluoromethyl anion was trapped as Meisenheimer complex 2 on heating a mixture of potassium trifluoroacetate and 1,3,5-trinitrobenzene (TNB) in DMF or DMSO. Treatment of 2 with tert -butylhypochlorite afforded 1-trifluoromethyl-2,4,6-trinitrobenzene ( 3 ).
openaire   +1 more source

Polymorphism of 1,3,5‐Trinitrobenzene Induced by a Trisindane Additive

Angewandte Chemie, 2004
The most stable is not necessarily the most easy to obtain! Two new stable crystal forms of the 120 year old compound sym-trinitrobenzene are reported. These elusive forms have been obtained by the use of an additive, trisindane, that can act as a mimic in the crystallization experiment.
THALLAPALLY, PK   +8 more
openaire   +3 more sources

Synthesis of Quinolonecarboxylic Acids from 1,3,5‐Trinitrobenzene.

ChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Sergei S. Vorob’ev   +6 more
openaire   +1 more source

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