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Shapley Additive Explanation for Local Class Differentiation: Local Explainability for Class Differentiation in Classification Models

Advanced Intelligent Systems, EarlyView.
An instance‐level, model‐agnostic explanation of class differentiation is introduced through SHAP‐LCD, linking probability shifts to feature‐wise Shapley contributions. The method operates on tabular and image data and is released in a fully reproducible implementation, offering a transparent way to examine, at each instance, why predictive models ...
Roxana M. Romero Luna, Hugo A. Ordoñez Erazo, Carlos A. Cobos Lozada   +2 more
wiley   +1 more source

Linearly acenaphthylene-fused pentacene exhibiting efficient singlet fission. [PDF]

Chem Sci
Arvidson J, Shaikh S, Tanaka M, Pawale T, Dawson A, Li X, Nesterov VN, Kobori Y, Das S, Wang H.   +9 more
europepmc   +1 more source

Azulene as Anomaly in Triplet-State Engineering Via Bromination and/or Carbonylation: Internal Conversion Overrides Intersystem Crossing

Claire Tonnelé, David Casanova
openalex   +1 more source

Iridium(III) Complexes Bearing Pyrene- and Anthracene-Functionalized Ligands-Photophysics and Application Potential in Photocatalysis, Triplet-Triplet Annihilation Upconversion, Photodynamic Therapy, and Photoactivated Chemotherapy. [PDF]

Molecules
Kryczka A, Choroba K, Palion-Gazda J, Machura B.   +3 more
europepmc   +1 more source

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Triplet State of DNA

Journal of Chemical Physics, 1967
Additional proof has been obtained for the fact that the triplet state in DNA and poly dAT resides at the thymine residue by comparing the intensities of the triplet ESR and phosphorescence signals from DNA's from various sources having different (A+T)/(G+C) ratios.
A A Lamola, J Eisinger, Yamane T
exaly   +3 more sources

Carotenoid triplet state lifetimes

Journal of Photochemistry and Photobiology B: Biology, 2000
Carotene and xanthophyll triplet lifetimes are found to depend on the concentration of the parent molecule. These results account for some of the variations in carotenoid triplet lifetimes reported previously. The rate constants obtained for ground state quenching correlate with the number of conjugated double bonds, the longer chain systems having ...
E J Land, David J Mcgarvey, T George Truscott   +2 more
exaly   +3 more sources

The triplet states of AlCl

Journal of Molecular Spectroscopy, 1989
The 0-0 band of the a3Πr-X1Σ+ transition has been fully analyzed. The b3Σ state observed by Sharma (Astrophys. J. 113, 210–218 (1951)) is shown to be a 3Δ state and the analysis of the 0-0, 0–1, and 0–2 bands of the b3Δ-a3Πr transition has been completed.
Mahieu, Emmanuel, DUBOIS, Iwan, BREDOHL, Harald   +2 more
openaire   +1 more source

Triplet states in photosynthesis

Biochemical and Biophysical Research Communications, 1974
Abstract A comparison of zero field splitting (ZFS) and spin polarization of triplet spectra of bacteriochlorophyll a in vitro and in vivo provides support for the special pair model of photoreactive chlorophyll in photosynthetic bacteria.
R A, Uphaus, J R, Norris, J J, Katz
openaire   +2 more sources

The triplet state of pyridoxal

Biochemical and Biophysical Research Communications, 1968
Abstract The absorption spectra, as well as the relative distribution of the structures of pyridoxal in aqueous solution, have been investigated in several laboratories ( Williams and Neilands, 1954 ; Metzler and Snell, 1955 ; Anderson and Martell, 1964) .
J E, Wampler, J E, Churchich
openaire   +2 more sources