Results 51 to 60 of about 292,062 (298)

More Than 50-Fold Enhanced Nonlinear Optical Response of Porphyrin Molecules in Aqueous Solution Induced by Mixing Base and Organic Solvent

open access: yesApplied Sciences, 2021
The difference absorption spectrum (DAS) of porphyrin molecules (tetraphenyl-porphyhrin sulfonic acid, TPPS) in aqueous solution induced by continuous wave laser irradiation has been reported previously.
Satoshi Imura   +2 more
doaj   +1 more source

Pariser-Parr-Pople Model based Investigation of Ground and Low-Lying Excited States of Long Acenes

open access: yes, 2013
Several years back Angliker et al [Chem. Phys. Lett. 1982, 87, 208] predicted nonacene to be the first linear acene with the triplet state $1^{3}B_{2u}$ as the ground state, instead of the singlet $1^{1}A_{g}$ state. However, contrary to that prediction,
Chakraborty, Himanshu, Shukla, Alok
core   +1 more source

Radiative cascade from quantum dot metastable spin-blockaded biexciton [PDF]

open access: yes, 2010
We detect a novel radiative cascade from a neutral semiconductor quantum dot. The cascade initiates from a metastable biexciton state in which the holes form a spin-triplet configuration, Pauli-blockaded from relaxation to the spin-singlet ground state ...
B. D. Gerardot   +8 more
core   +2 more sources

Near‐Infrared Emitting Lanthanide Catecholate Giant Single Crystals – Morphology Control and Photon Down‐Conversion

open access: yesAdvanced Functional Materials, EarlyView.
Controlled syntheses of lanthanide coordination polymers based on the dihydroxybenzoquinone (DHBQ) organic linker afforded large single crystals of Ln‐DHBQ CPs (Ln = Yb, Nd). A novel structural variant of Yb‐DHBQ is identified by means of single crystal diffraction analysis.
Marina I. Schönherr   +7 more
wiley   +1 more source

Ligand triplet energy escape in lanthanide complexes for developing luminescent molecular thermometers

open access: yesCommunications Chemistry
Luminescent lanthanide complexes can exhibit temperature-sensitive metal-centered emission due to energy transfer quenching from the lanthanide to the ligand triplet states, which have been promising application in emission lifetime-based thermometers ...
Yusaku Yamaguchi   +5 more
doaj   +1 more source

Obtaining triplet-triplet absorption spectra and triplet lifetimes of long-lived molecules with a UV-Visible spectrophotometer

open access: yesJournal of Photochemistry and Photobiology
A simple method for obtaining triplet-triplet absorption (TTA) spectra and triplet state (T1) lifetimes of long-lived triplets is presented and demonstrated with the polycyclic aromatic hydrocarbon coronene (both normal and perdeuterated forms) in a ...
Tiago Palmeira   +5 more
doaj   +1 more source

Roles of Localized Electronic Structures Caused by π Degeneracy Due to Highly Symmetric Heavy Atom‐Free Conjugated Molecular Crystals Leading to Efficient Persistent Room‐Temperature Phosphorescence

open access: yesAdvanced Science, 2019
Conjugated molecular crystals with persistent room‐temperature phosphorescence (RTP) are promising materials for sensing, security, and bioimaging applications.
Shuzo Hirata
doaj   +1 more source

A reatividade do estado excitado triplete de 1,3-indanodiona em benzeno Triplet excited state reactivity of 1,3-indandione in benzene solution

open access: yesQuímica Nova, 2007
Rate constants for the quenching of 1,3-indandione (1) triplet by olefins and by hydrogen and electron donors were obtained employing the laser flash photolysis technique in benzene solution.
Frances R. dos Santos   +3 more
doaj   +1 more source

Cotunneling Spectroscopy in Few-Electron Quantum Dots

open access: yes, 2004
Few-electron quantum dots are investigated in the regime of strong tunneling to the leads. Inelastic cotunneling is used to measure the two-electron singlet-triplet splitting above and below a magnetic field driven singlet-triplet transition.
A. C. Gossard   +4 more
core   +1 more source

Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76)

open access: yesAdvanced Functional Materials, EarlyView.
Luminescent MOF‐76 materials based on Eu(III) and mixed Eu(III)/Y(III) show rapid and reversible changes in emission intensity in response to O2 with very short response times. The effect is based on triplet quenching of the linker ligands that act as photosensitizers. Average emission lifetimes of a few milliseconds turn out to be mostly unaffected by
Zhenyu Zhao   +5 more
wiley   +1 more source

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