Results 101 to 110 of about 981,982 (189)

Iron‐Photocatalyzed Alkene Chloroaminoxylation: A Platform for Orthogonally Activatable Building Blocks

open access: yesAngewandte Chemie, EarlyView.
An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri   +5 more
wiley   +2 more sources

Ac‐SDKP modulates apoptosis via HSP27 and the FAS/FASL and mitochondrial axes

open access: yesAnimal Models and Experimental Medicine, EarlyView.
Schematic diagram of Ac‐SDKP regulating the FAS/FASL and mitochondrial apoptosis pathways via HSP27. Ac‐SDKP inhibits HSP27 expression, activates the FAS/FASL pathway and Caspase‐3 signaling, increases Caspase‐8 and Caspase‐3 expression, and induces cell apoptosis.
Wenxin Guo   +13 more
wiley   +1 more source

Step‐Associated Cu‐Ceria Interfaces Enhance Catalytic Activity and Selectivity

open access: yesAngewandte Chemie, EarlyView.
The catalytic activity and selectivity of supported Cu nanoparticles depends on their interfacial environments, with Cu nanoparticles at step‐associated environments converting CO2 to methanol much faster than those on terrace facets, indicating that step sites create more active metal–oxide interfaces.
Shuxuan Feng   +12 more
wiley   +2 more sources

Deng Atem [PDF]

open access: yes
: Deng Atem witnessed his village being burned and people being killed. He was seven years old when the militia came into his village. “Lost Boys Found” is an ongoing, interdisciplinary project that is collecting, recording and archiving the oral ...

core  

Growth Differentiation Factor 15 as a Cerebrospinal Fluid Biomarker for the Diagnosis and Prognosis of Leptomeningeal Metastasis

open access: yesAnnals of Neurology, EarlyView.
Objective As leptomeningeal metastasis (LM) has a poor prognosis, reliable cerebrospinal fluid (CSF) diagnostic biomarkers are urgently needed. This study evaluated the diagnostic value of CSF growth differentiation factor 15 (GDF15) in LM from lung adenocarcinoma (LUAD) and breast cancer (BC).
Haoyu Ruan   +12 more
wiley   +1 more source

Single‐Atom Control of Aromaticity and Excited‐State Dynamics in Endohedral Zirconium–Antimony Zintl Clusters

open access: yesAngewandte Chemie, EarlyView.
Single‐atom growth from [Zr@Sb12]2− to [Zr@Sb13]3− disrupts the closed‐shell S2P6 superatomic configuration and markedly attenuates three‐dimensional (3D) aromaticity. Ultrafast spectroscopy further links stronger spherical aromaticity to slower excited‐state relaxation, establishing an atom‐resolved structure‐aromaticity‐dynamics relationship ...
Yun Zhang   +7 more
wiley   +2 more sources

Shan Deng & Dr. Wei Deng - Sunday Live Concert

open access: yes, 2008
Sunday Live Concert July 6, 2008, Stanley Burbury Theatre, Hobart Direct broadcast on ABC Classic FM Performers: Shan Deng (piano) Dr. Wei Deng (pipa) This concert presented a series of traditional pieces for piano and pipa both
Shan Deng (14735122)
core  

Scaffold‐Free Living Cellular Structure With Omnidirectional Architectures

open access: yesAdvanced NanoBiomed Research, EarlyView.
Hydrogel lumen confinement enables the direct formation of mechanically stable, scaffold‐free cellular filaments under entirely aqueous, phototoxicity‐free conditions. These processable living building blocks support omnidirectional assembly into complex three‐dimensional architectures, providing a simple and versatile platform for scaffold‐free ...
Jing Ma   +7 more
wiley   +1 more source

Cobalt‐Catalyzed [2σ+2π] Cycloaddition via Site‐Selective Capture of Bicyclobutane Diradical

open access: yesAngewandte Chemie, EarlyView.
We report a Co(II)‐catalyzed strategy that combines thermal activation of bicyclo[1.1.0]butane (BCBs) with site‐selective radical capture to furnish head‐to‐head fused bicyclo[2.1.1]hexanes via [2σ+2π] cycloaddition with indoles. Detailed mechanistic studies (31P NMR, EPR, CV, and DFT) support the catalytic pathway, while phosphine‐oxide trapping and X‐
Tanmayee Nanda   +8 more
wiley   +2 more sources

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