Results 221 to 230 of about 135,103 (314)

Solvatomorphism and Anion Effects in Fluorinated MnIII Spin Crossover Complexes

open access: yesEuropean Journal of Inorganic Chemistry, Accepted Article.
Eight new MnIII salts of the [MnIII(3,5‐diF‐sal2323)]X complex are reported, of which four showed thermal spin crossover (SCO), where X− = PF6− (1a – 1c), AsF6− (2), NO3− (3), Br− (4), BF4− (5), OTf− (6). Solvatomorphism is observed in the PF6− salt, revealing one complex which undergoes gradual spin crossover (1a·0.33CH3CN), one that is fully high ...
Grace Genevieve Morgan   +8 more
wiley   +1 more source

Predicting Flu Trends using Twitter data [PDF]

open access: green, 2011
Harshavardhan Achrekar   +4 more
openalex   +1 more source

Intense Absorption of Phosphorescent Biscyclometalated Ir(III) Complex with Triarylborane‐Bound 2,2’‐Bipyridine Ligand

open access: yesEuropean Journal of Inorganic Chemistry, Accepted Article.
A Monocationic biscyclometalated Ir(III) complex with triarylborane‐bound 2,2′‐bipyridine was designed and synthesized, and its photophysical properties were investigated. The triarylborane–Ir(III) complex exhibited significantly enhanced absorption in the 300–400 nm region compared to pristine biscyclometalated Ir(III) complexes, attributed to ...
Ryo Fukumoto   +6 more
wiley   +1 more source

Synthesis of [(3,4,5‐F3C6H2)(4‐nBuC6H4)2C][HCB11Cl11]: A Much More Soluble Version of the Trityl Cation with Slightly Higher Lewis Acidity

open access: yesEuropean Journal of Inorganic Chemistry, Accepted Article.
A new triarylmethyl cation (*Tr+), designed to closely mimic Ph3C+ in reactivity has been prepared as a [HCB11Cl11]‐ salt. *Tr+ very slightly exceeds the Lewis acidity of Ph3C+ in chloride and hydride transfer reactions, but possesses two orders of magnitude higher solubility in organic solvents of low polarity.
Jack P. Raker, Oleg V. Ozerov
wiley   +1 more source

Reactivity of an ortho‐Phenylene‐bridged Al/P Frustrated Lewis Pair Towards Small Molecules

open access: yesEuropean Journal of Inorganic Chemistry, Accepted Article.
Frustrated Lewis Pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. In this paper, we present the first ortho‐phenylene bridged Al/P‐based FLP with only one phosphine moiety. The title compound was employed in various reactions with small molecules featuring different functional ...
Melina E. A. Dilanas, Frank Breher
wiley   +1 more source

Home - About - Disclaimer - Privacy