Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo +14 more
wiley +2 more sources
Oxygen-Pressure-Limited Recovery of the Hematite α‑Fe<sub>2</sub>O<sub>3</sub>(0001) Surface from a Reduced Fe<sub>3</sub>O<sub>4</sub>(111)-like Layer. [PDF]
Kumar N, Blatnik M, Čechal J.
europepmc +1 more source
Oxidation‐Induced Internal Chemical Patterning in Copper–Gold Nanoalloys
Surface oxidation suppresses Au surface segregation and redirects Au transport to twin boundaries, replacing conventional core–shell formation with internal chemical patterning. Driven by Cu–Au mixing thermodynamics, defect‐mediated uphill diffusion creates alternating Au‐rich and Cu‐rich lamellae, revealing oxidation as a chemical pump for bulk ...
Zhikang Zhou +11 more
wiley +1 more source
The silver nanoparticle morphologies are identified thanks to ab initio models, including original families of defects and complex motifs, compared to measurements provided at targeted sizes (309, 561, 742, and 923 atoms). The crossings between structures to within a few atoms have been predicted due to very accurate computational conditions, which are
Nathalie Tarrat, David Loffreda
wiley +1 more source
Operando EC‐STM reveals that an NHC‐based SMOF on Au(111), initially frozen in interconnected 1D chains, dynamically reconfigures under cathodic bias into a fluxional structure bearing undercoordinated Au sites while abstracting Au atoms from the support.
Paulina Wira +12 more
wiley +1 more source
On-Chip Tuning of Superconductivity in Fullerides via Current-Driven Rb<sup>+</sup> Intercalation. [PDF]
Shchukin KP +8 more
europepmc +1 more source
Surface termination effects on Raman spectra of Ti3C2Tx MXenes: an in situ UHV analysis
SURFACE TERMINATION EFFECTS ON RAMAN SPECTRA OF TI3C2TX MXENES: AN IN SITU UHV ANALYSIS Surface termination effects on Raman spectra of Ti3C2Tx MXenes: an in situ UHV analysis / Plaickner, Julian (Rights reserved) (-
Koch, Norbert +5 more
core
Consensus-based feature selection and Bayesian-optimized stacking ensembles for comprehensive fault diagnosis in series-compensated ultra-high-voltage power systems. [PDF]
Nawaz R, Qamar A, Wadood A, Albalawi H.
europepmc +1 more source
Disentangling Molecular and Intrinsic Emission in Citric Acid–Urea Carbon Dots
Citric acid–urea thermal reactions under equimolar and urea‐rich conditions generate distinct fluorophore populations alongside carbon dots. Size‐exclusion chromatography reveals precursor‐dependent molecular species, whereas extended dialysis separates low‐molecular‐weight fluorophores from retained carbon dots. Despite the different synthetic regimes,
Chiara Olla +12 more
wiley +1 more source
Direct Experimental Evidence of Transient Au<sup>δ+</sup> Oxide in Au Electrooxidation. [PDF]
Redondo J +12 more
europepmc +1 more source

