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Infrared Spectroscopy of Pentagon-Containing PAHs: Indenyl and Fluorenyl Anions and Indenyl Cation. [PDF]
Wenzel G +6 more
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Controlling the sign of optical forces using metaoptics. [PDF]
Afridi A, Melo B, Meyer N, Quidant R.
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Toward a coherent ultracold chemistry
Science, 2022Magnetic fields can be used to change chemical reaction rates by a factor of ...
Simon L, Cornish, Jeremy M, Hutson
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Chemistry at ultracold temperatures
Chemical Physics Letters, 2001Abstract The reaction F+H 2 →FH+H is studied quantum mechanically at ultralow temperatures. The low temperature limit of its rate coefficient is controlled by the attractive van der Waals interaction and quantum mechanical threshold effects. When the fine-structure splitting of the fluorine atom is neglected, the rate coefficient passes through a ...
N. Balakrishnan, A. Dalgarno
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Manipulation of Ultracold Chemistry
Frontiers in Optics 2010/Laser Science XXVI, 2010I will discuss the molecular physics underlying recent experimental observations of, and control over, chemical reactions at JILA. For these polar species, possible handles for control include the quantum statistics of the molecules, the temperature, applied electric fields, and confinement in reduced-dimensional geometry.
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Ultracold chemistry: No longer a disappearing act
Physics Today, 2020Until now, researchers have struggled to study reactions whose products they couldn’t see.
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Towards ultracold chemistry; manipulation of polar molecules with electric fields
International Quantum Electronics Conference, 2005., 2005Deceleration and trapping of polar molecules using time-varying electric fields is described. Decelerated ND3 and OH molecules are trapped in an electrostatic trap, slow beams of ammonia are injected in a storage ring and have also been used for testing micro-structured optical elements and for high-resolution spectroscopy.
J. Kupper +7 more
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Ultracold chemistry in supersonic beams
Physics Today, 2012As the relative motions of reactants become small enough, quantum effects manifest themselves.
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Quantum weirdness sends ultracold chemistry into overdrive
New Scientist, 2011Atoms that are normally aloof get cosy at cold temperatures, which could help explain how chemical reactions get started in the cold, diffuse wasteland of interstellar ...
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State-to-state chemistry for three-body recombination in an ultracold rubidium gas
Science, 2017Tracking a trio of rubidium atoms Crossed molecular beams have provided decades' worth of knowledge into how quantum mechanics governs chemical reactivity. Nonetheless, the technique is generally limited to the collision of two partners. Wolf et al.
Joschka Wolf +8 more
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