Results 121 to 130 of about 28,047 (231)

A de‐novo Approach Towards Divergent [3+2π/σ] Photocycloadditions of Nitrones via Assembly‐Controlled Kinetic Electron Transfer Gating

open access: yesAngewandte Chemie, EarlyView.
A metal‐free photocatalytic platform converts nitrones into 4‐isoxazolines and oxa–aza–bicycloheptanes through divergent [3+2π/σ] cycloadditions. Assembly‐controlled kinetic electron transfer gating dictates substrate activation, enabling selective reactivity beyond thermodynamic expectations.
Nayan Saha   +6 more
wiley   +2 more sources

Underdevelopment in Ethiopia

open access: yes, 2004
The papers brought together in this volume represent a selection from my writings, and span a period of thirty years (1967-97). There was, however, a significant break in this long period, during which I wrote virtually nothing.
Chole, E.
core  

How Media Represent Australian Indigenous Business: Comparing Australian and International Coverage

open access: yesAustralian Journal of Social Issues, EarlyView.
ABSTRACT Media representations of Indigenous business shape public perceptions, investor confidence and consumer demand, influencing how Indigenous enterprises are valued and understood. This Indigenous‐led study systematically reviews grey literature on Australian Aboriginal and Torres Strait Islander businesses published between 2006 and 2024 ...
Maria Raciti   +3 more
wiley   +1 more source

A Mesoionic Platform for Persistent Anionic Nitrogen‐Centered Radicals

open access: yesAngewandte Chemie, EarlyView.
Charge did not meet spin: Mesoionic 1,2,3‐triazines undergo reversible one‐electron reduction to persistent anionic nitrogen‐centered radicals. Electron paramagnetic resonance, single‐crystal x‐ray diffraction, and calculations reveal nitrogen‐localized spin and structural reorganization, while crystalline salts show clean redox cycling.
Deepak Ranolia   +8 more
wiley   +2 more sources

Chirality‐Driven Piezocatalysis in MOFs: Achieving Efficient Cocatalyst‐Free Hydrogen Evolution

open access: yesAngewandte Chemie, EarlyView.
We report a chirality‐driven post‐synthetic modification strategy that grafts chiral L‐histidine (L‐His) onto the Hf6 clusters of MOF‐808(Hf), which significantly boosts the piezoelectricity and charge transfer efficiency, thus significantly enhancing the piezocatalytic performance of MOF‐808(Hf).
Yali Ma   +7 more
wiley   +2 more sources

Capitalism and underdevelopment in Latin America

open access: yes
CAPITALISM AND UNDERDEVELOPMENT IN LATIN AMERICA Capitalism and underdevelopment in Latin America (-
Frank, André Gunder
core  

Photoactivated Platinum Complexes: Targeting Membrane Proteins and Organelles for Precision Cancer Therapy

open access: yesAngewandte Chemie, EarlyView.
This review highlights an emerging anticancer approach integrating platinum agents into photodynamic therapy (PDT) and photoactivated chemotherapy (PACT) systems, further augmented by cancer cell membrane‐ and organelle‐targeting. By directing photoactivated platinum complexes from nontargeted distribution to cancer cells or defined subcellular sites ...
Shu Chen   +3 more
wiley   +2 more sources

Underdevelopment, Development and the Future of Africa

open access: yes, 2017
In view of the resilience of Africa's underdevelopment, what do Africans make of their determined aspirations for development? The continent of Africa has constantly drawn global attention, most especially for both human and natural evils ...
Mawere, Munyaradzi
core  

The Problem of Patent Underdevelopment [PDF]

open access: yes, 2005
Commentators have long recognized that much of the work of commercializing an invention occurs after a patent is received. They have not recognized, however, that by the time market conditions make commercialization potentially attractive, the remaining ...
Abramowicz, Michael B.
core  

Axially Chiral Nonalternant Polycyclic Aromatic Hydrocarbon With Consecutive Pentagons Exhibiting Large Spin‐Polarized Current

open access: yesAngewandte Chemie, EarlyView.
Here we report two nonalternant polycyclic aromatic hydrocarbons (PAH) (1 and 2), which contain two and four consecutive pentagons, respectively. Under acidic conditions, 1 and 2 dimerize to afford the axially chiral dimers AC1 and AC2. The central azulene moiety in both 2 and AC2 shows an unusually short transannular bond of 1.366 Å.
Chang Wang   +3 more
wiley   +2 more sources

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