Results 51 to 60 of about 376,595 (201)

Bounded Rationality and Greenwashing: An Information‐Architecture Signalling Framework for Verification Frictions and the Disclosure–Performance Gap

open access: yesBusiness Strategy and the Environment, EarlyView.
ABSTRACT Green claims pervade corporate communications, yet their informational value varies because stakeholders process them under bounded rationality—scarce attention and costly verification. This paper develops a conceptual signalling framework in which three parameters—signal diagnosticity (D), verification frictions (V) and available attention (A)
Luca Lancini
wiley   +1 more source

Revisiting the Latin Vocabulary of Terminologia Histologica: II. Adjectives and Participles

open access: yesClinical Anatomy, EarlyView.
ABSTRACT Terminologia Histologica, the international standard nomenclature of human histology and cytology, contains 1093 Latin words that appear to be used as adjectives. Among these, we identified 56 (5%) with a variety of linguistic issues, including typographical or spelling errors, less favored spelling variants, and several unfortunate word ...
Paul E. Neumann   +7 more
wiley   +1 more source

Temporal Trends and Prognosis in Rotational Atherectomy: A Comparison of Contemporary and Traditional Eras

open access: yesCatheterization and Cardiovascular Interventions, EarlyView.
ABSTRACT Background Rotational atherectomy (RA) has undergone considerable technical modernization in recent years. This study evaluated whether RA performed in the contemporary era was associated with superior cardiovascular outcomes compared with the traditional era. Aims To compare the clinical characteristics and cardiovascular outcomes of patients
Ravi Vazirani   +15 more
wiley   +1 more source

Carba‐closo‐dodecaborates as Superchaotropic Anions

open access: yesChemistry – A European Journal, EarlyView.
The singly charged boron cluster anion CB11H12– forms strong inclusion complexes with cyclodextrins, interacts strongly with nonionic polymers, and serves as an effective transmembrane carrier, positioning itself as the smallest superchaotropic anion known to date. .
Andrea Barba‐Bon   +8 more
wiley   +1 more source

Ir Complexes With Mixed‐Valent Bidentate Ligands: From Complex Synthesis to Catalytic Application

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The bidentate ligands Ph2P(E)NHPPh2 (E = S, Se) feature phosphorous atoms in two different oxidation states and provide the potential to tune chemical reactivity through the choice of donor E. The mononuclear complexes [Ir(COD){κ2‐P,E‐Ph2P(E)NPPh2}] (E = S 1a, Se 1b) were prepared from the dimer [IrClCOD]2 (COD = 1,5‐cyclooctadiene) and the ...
C. Gabriela Morales Salas   +4 more
wiley   +1 more source

Accelerating SCF Convergence Through Equivariant Density‐Matrix Learning and Analytic Refinement

open access: yesChemistry – A European Journal, EarlyView.
Machine learning predicts physically consistent one‐electron reduced density matrices that provide efficient initial guesses for self‐consistent field calculations. Across diverse molecular systems, this warm‐start strategy reduces the required self‐consistent‐field (SCF) iterations by up to 80% while preserving converged energies and atomic forces ...
Zuriel Y. Yescas‐Ramos   +2 more
wiley   +1 more source

Azoimidazolium Salts as a Platform for Persistent Neutral Aminyl Radicals and Mesoionic Carbene Au(I) Complexes as Cell‐Permeable Fluorophores

open access: yesChemistry – A European Journal, EarlyView.
Strategic electronic matching between imidazolium salts and aryldiazonium salts enables a chromatography‐free route to versatile azoimidazolium scaffolds. Fine‐tuning the substituents unveils a powerful dichotomy: strong ─OMe resonance stabilizes highly persistent neutral aminyl radicals (up to 3 weeks), whereas the superior ─NMe2 donor strength yields
Diego Dusso   +6 more
wiley   +1 more source

Synthesis and characterization of amphiphilic nitroxide 1,1,3,3–tetraethylisoindoline–2–oxyl–5–sodium sulfonate (TEIOSNa)

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The synthesis and characterization of an amphiphilic nitroxide to be used as a controlling agent in a nitroxide‐mediated living radical polymerization in aqueous dispersion media is presented. In the first stage of nitroxide synthesis (phthalimide protection), two reaction methods were employed: traditional and microwave.
Enrique García‐Leal   +3 more
wiley   +1 more source

Design and implementation of a 3D‐printed modular distillation tower for experimental teaching in chemical engineering

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Several authors have reported the disconnection between the skills, abilities, and attitudes of graduates from STEM careers with the current needs of the labour market. In science and engineering fields, research has found the need for interdisciplinary approaches that encourage meaningful learning.
Úrsula Manríquez‐Tolsá   +7 more
wiley   +1 more source

Chemical engineering as an essential element of industrial biotechnology in Mexico: New aims in research and university education

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract On the centennial of higher education in Chemical Engineering in Mexico, it is pertinent to revisit the key stages that have contributed to its consolidation as a vital discipline for the nation's scientific and technological advancement. Although the initial mission of chemical engineering education was primarily oriented toward the training ...
Agustín López Munguía   +3 more
wiley   +1 more source

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